Evidence map›Paper›PMID 31329325›Full record

ArticleAngewandte Chemie (International ed. in English)2019

Protein-like Enwrapped Perylene Bisimide Chromophore as a Bright Microcrystalline Emitter Material.

David Schmidt, Matthias Stolte, Jasmin Süß, Andreas Liess, Vladimir Stepanenko, Frank Würthner

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Brightness of fluorescent organic nanomaterials.Chemical Society reviews · 2023
    Review
  5. Article
  6. Review
  7. Review
  8. Article
  9. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

David SchmidtInstitut für Organische Chemie & Center for Nanosystems Chemistry, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.ORCID 0000-0001-8118-7935
Matthias StolteInstitut für Organische Chemie & Center for Nanosystems Chemistry, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Jasmin SüßInstitut für Organische Chemie & Center for Nanosystems Chemistry, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Andreas LiessInstitut für Organische Chemie & Center for Nanosystems Chemistry, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Vladimir StepanenkoInstitut für Organische Chemie & Center for Nanosystems Chemistry, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Frank WürthnerInstitut für Organische Chemie & Center for Nanosystems Chemistry, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.ORCID 0000-0001-7245-0471

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Strongly emissive solid-state materials are mandatory components for many emerging optoelectronic technologies, but fluorescence is often quenched in the solid state owing to strong intermolecular interactions. The design of new organic pigments, which retain their optical properties despite their high tendency to crystallize, could overcome such limitations. Herein, we show a new material with monomer-like absorption and emission profiles as well as fluorescence quantum yields over 90 % in its crystalline solid state. The material was synthesized by attaching two bulky tris(4-tert-butylphenyl)phenoxy substituents at the perylene bisimide bay positions. These substituents direct a packing arrangement with full enwrapping of the chromophore and unidirectional chromophore alignment within the crystal lattice to afford optical properties that resemble those of their natural pigment counterparts, in which chromophores are rigidly embedded in protein environments.

Indexed as

crystal engineeringdyesfluorescence quantum yieldperylene bisimidessolid-state emitters

Identifiers

PMID31329325
PMCPMC6772080

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.