ArticleJournal of the American Chemical Society2019
Enhanced Rates of C-H Bond Cleavage by a Hydrogen-Bonded Synthetic Heme High-Valent Iron(IV) Oxo Complex.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Activation of the Ground and Excited State of a Luminescent Osmium(VI) Dioxo Dicyano Complex with Lewis Acids.Journal of the American Chemical Society · 2026Article
- Multisite Proton-Coupled Electron Transfer at a Keggin-Type Polyoxotungstate.Journal of the American Chemical Society · 2026Article
- Dynamic electronic modulation of single-atom Fe sites with p-block metal coordination enables highly selective generation of FeNature communications · 2025Article
- Dinuclear Copper Complex with a Pyridazine-Bridged Octadentate Ligand: Monooxygenase Activity and Characterization of Copper-Oxygen Intermediates.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Experimental electronic structures of the FeProceedings of the National Academy of Sciences of the United States of America · 2025Article
- Synthesis, characterization and reactivity of a Mn(III)-hydroxido complex as a biomimetic model for lipoxygenase.Journal of inorganic biochemistry · 2024Article
- Enhanced Reactivities of Iron(IV)-Oxo Porphyrin Species in Oxidation Reactions Promoted by Intramolecular Hydrogen-Bonding.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Heme-copper and Heme OJournal of inorganic biochemistry · 2023Review
- A Porphyrin Iron(III) π-Dication Species and its Relevance in Catalyst Design for the Umpolung of Nucleophiles.Angewandte Chemie (International ed. in English) · 2023Article
- The role of basicity in selective C-H bond activation by transition metal-oxidos.Dalton transactions (Cambridge, England : 2003) · 2023Review
- Article
- C-H Bond Cleavage by Bioinspired Nonheme Metal Complexes.Inorganic chemistry · 2021Review
- Semiempirical method for examining asynchronicity in metal-oxido-mediated C-H bond activation.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- Bimodal Evans-Polanyi Relationships in Hydrogen Atom Transfer from C(spJournal of the American Chemical Society · 2021Article
- Catalytic Oxygenation of Hydrocarbons by Mono-μ-oxo Dicopper(II) Species Resulting from O-O Cleavage of Tetranuclear CuAngewandte Chemie (International ed. in English) · 2021Article
- Deciphering the origin of million-fold reactivity observed for the open core diiron [HO-FeChemical science · 2020Article
- Diazaphosphinanes as hydride, hydrogen atom, proton or electron donors under transition-metal-free conditions: thermodynamics, kinetics, and synthetic applications.Chemical science · 2020Article
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Authors and funding
3 authors.
Funding
Abstract
Secondary coordination sphere interactions are critical in facilitating the formation, stabilization, and enhanced reactivity of high-valent oxidants required for essential biochemical processes. Herein, we compare the C-H bond oxidizing capabilities of spectroscopically characterized synthetic heme iron(IV) oxo complexes, F
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