ArticleChemistry (Weinheim an der Bergstrasse, Germany)2019
Phosphorus Post-Functionalization of Diphosphahexaarenes.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Transformation of the Phosphorus Atom in Hexacyclic Polyaromates and Its Impact on Physicochemical Properties.The Journal of organic chemistry · 2026Article
- The role of main group elements in shaping the properties of linearly-fused heterohexaarenes.Chemical communications (Cambridge, England) · 2025Article
- Synthesis, Post-Functionalization and Properties of Diphosphapentaarenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- En Route Towards the Control of Luminescent, Optically-Active 3D Architectures.Angewandte Chemie (International ed. in English) · 2021Article
- Cationic Organophosphorus Chromophores: A Diamond in the Rough among Ionic Dyes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
- Phosphorus Post-Functionalization of Diphosphahexaarenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Diphosphahexaarenes are highly stable π-extended frameworks containing two six-membered phosphorus heterocycles that have emerged recently. Herein, we present a detailed investigation on the post-functionalization reactions of their phosphorus centers with special emphasis on the selectivity of the processes and the impact of the phosphorus functionalizations into the physicochemical properties. These studies reveal that indeed the phosphorus atoms of the diphosphahexaarenes are readily available to be functionalized with quaternizing and oxidizing agents as well as borane groups without compromising the stability of the system. In addition, the optoelectronic properties of the diphosphahexaarenes are impacted by the phosphorus post-modifications.
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Registered trials
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