ArticleJournal of the American Chemical Society2019
A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed.
- Formation of Supramolecular Structures in Oxidation Processes Catalyzed by Heteroligand Complexes of Iron and Nickel: Models of Enzymes.International journal of molecular sciences · 2025Article
- Reactivity Inside Molecular Flasks: Acceleration Modes and Types of Selectivity Obtainable.Angewandte Chemie (International ed. in English) · 2024Review
- Substrate scope driven optimization of an encapsulated hydroformylation catalyst.Catalysis science & technology · 2024Article
- Picking the lock of coordination cage catalysis.Chemical science · 2023Review
- A substrate descriptor based approach for the prediction and understanding of the regioselectivity in caged catalyzed hydroformylation.Faraday discussions · 2023Article
- Photocatalysis in Water-Soluble Supramolecular Metal Organic Complex.Molecules (Basel, Switzerland) · 2023Review
- High-efficiency gold recovery by additive-induced supramolecular polymerization of β-cyclodextrin.Nature communications · 2023Article
- Synergistic Porosity and Charge Effects in a Supramolecular Porphyrin Cage Promote Efficient Photocatalytic COAngewandte Chemie (International ed. in English) · 2023Article
- Distinct selectivity inside self-assembled coordination cages.Frontiers in chemistry · 2023Review
- Altering the Properties of Spiropyran Switches Using Coordination Cages with Different Symmetries.Journal of the American Chemical Society · 2022Article
- Differentiable Formation of Chiroptical Lanthanide Heterometallic LnChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Site-selective reactions mediated by molecular containers.Beilstein journal of organic chemistry · 2022Review
- Supramolecular Strategies for the Recycling of Homogeneous Catalysts.Chemistry, an Asian journal · 2021Review
- Heteroleptic Ligation by an endo-Functionalized Cage.Angewandte Chemie (International ed. in English) · 2021Article
- Selective aldehyde reductions in neutral water catalysed by encapsulation in a supramolecular cage.Chemical science · 2021Article
- Exploiting host-guest chemistry to manipulate magnetic interactions in metallosupramolecular MChemical science · 2021Article
- Selectivity of Rh⋅⋅⋅H-C Binding in a σ-Alkane Complex Controlled by the Secondary Microenvironment in the Solid State.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Design and Applications of Water-Soluble Coordination Cages.Chemical reviews · 2020Article
- Topological prediction of palladium coordination cages.Chemical science · 2020Article
- One Guest or Two? A Crystallographic and Solution Study of Guest Binding in a Cubic Coordination Cage.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
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4 authors.
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Abstract
Performing selective transformations on complex substrates remains a challenge in synthetic chemistry. These difficulties often arise due to cross-reactivity, particularly in the presence of similar functional groups at multiple sites. Therefore, there is a premium on the ability to perform selective activation of these functional groups. We report here a supramolecular strategy where encapsulation of a hydrogenation catalyst enables selective olefin hydrogenation, even in the presence of multiple sites of unsaturation. While the reaction requires at least one sterically nondemanding alkene substituent, the rate of hydrogenation is not sensitive to the distance between the alkene and the functional group, including a carboxylate, on the other substituent. This observation indicates that only the double bond has to be encapsulated to effect hydrogenation. Going further, we demonstrate that this supramolecular strategy can overcome the inherent allylic alcohol selectivity of the free catalyst, achieving supramolecular catalyst-directed regioselectivity as opposed to directing-group selectivity.
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