ArticleAngewandte Chemie (International ed. in English)2019
Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 63 papers.
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Who cites it
63 citing papers in PubMed.
- Mechanistic Diversity in Photoexcited Radical Redox Chemistry: A Critical Evaluation.Angewandte Chemie (International ed. in English) · 2026Review
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- Photophysics of Doubly Reduced Quinacridone Dyes: Toward Redox Reactivity Activated by Red Light.Artificial photosynthesis (Washington, D.C.) · 2026Article
- Photoelectrochemical HChemical science · 2026Review
- Lucigenin: a strongly oxidizing dicationic photocatalyst for the direct azolation of arenes.Chemical science · 2026Article
- Mechanistic Design in Photocatalysis.Accounts of chemical research · 2026Article
- Microwave-alkali co-activated persulfate enables minute-scale fertilization of food waste with high fulvic-like acid yield.Nature communications · 2026Article
- Interfacial Photoelectrochemistry in Organic Synthesis.Angewandte Chemie (International ed. in English) · 2025Review
- Rapid Electrochemical Assessment of Excited-State Quenching Dynamics.ACS catalysis · 2025Article
- Persistent Boryl Radicals as Highly Reducing Photoredox Catalysts for Debrominative Borylations.Journal of the American Chemical Society · 2025Article
- Electrochemical heteroarylation and amidation of alkanes using activated glassy carbon electrodes without mediators.Communications chemistry · 2025Article
- Excited Organic Radicals in Photoredox Catalysis.JACS Au · 2025Review
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- Electrochemical Non-Directed Arene C-H Amination.ChemCatChem · 2024Article
- Visible-Light Photocatalytic C-H Amination of Arenes Utilizing Acridine-Lewis Acid Complexes.Journal of the American Chemical Society · 2024Article
- Electrophotocatalytic hydrogenation of imines and reductive functionalization of aryl halides.Nature communications · 2024Article
- Selective C(spNature communications · 2023Article
- Photoelectrochemical oxidative C(spNature communications · 2023Article
- Electrochemical Late-Stage Functionalization.Chemical reviews · 2023Review
- Ketyl Radical Coupling Enabled by Polycyclic Aromatic Hydrocarbon Electrophotocatalysts.Journal of the American Chemical Society · 2023Article
3 more citing papers are in PubMed but not listed here.
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7 authors.
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Abstract
Visible-light photocatalysis and electrocatalysis are two powerful strategies for the promotion of chemical reactions. Here, these two modalities are combined in an electrophotocatalytic oxidation platform. This chemistry employs a trisaminocyclopropenium (TAC) ion catalyst, which is electrochemically oxidized to form a cyclopropenium radical dication intermediate. The radical dication undergoes photoexcitation with visible light to produce an excited-state species with oxidizing power (3.33 V vs. SCE) sufficient to oxidize benzene and halogenated benzenes via single-electron transfer (SET), resulting in C-H/N-H coupling with azoles. A rationale for the strongly oxidizing behavior of the photoexcited species is provided, while the stability of the catalyst is rationalized by a particular conformation of the cis-2,6-dimethylpiperidine moieties.
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