ArticleJournal of the American Chemical Society2019
Sulfonyl Fluoride Synthesis through Electrochemical Oxidative Coupling of Thiols and Potassium Fluoride.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 40 papers.
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Who cites it
40 citing papers in PubMed.
- Alkyl sulfonyl fluorides as ambiphiles in the stereoselective palladium(II)-catalysed cyclopropanation of unactivated alkenes.Nature synthesis · 2026Article
- Guided phase transition for mitigating voltage hysteresis of iron fluoride positive electrodes in lithium-ion batteries.Nature communications · 2025Article
- Electrochemically promoted defluorinative sulfoximination and fluorosulfonylation of non-activated aryl fluorides at room temperature.Chemical science · 2025Article
- Carbamothioate-mediated Selectfluor™ oxidation for the synthesis of benzenesulfonyl fluorides in chalcone derivatives.RSC advances · 2025Article
- Routes to Pt Derivatives of High-Valent Sulfur Oxofluorides S(═O)Angewandte Chemie (International ed. in English) · 2025Article
- Electrochemical Conversions of Sulfenamides into Sulfonimidoyl- and Sulfondiimidoyl Fluorides.JACS Au · 2025Article
- Electrochemical Flow Reactors: Mass Transport, iR Drop, and Membrane-Free Performance with In-Line Analysis.ACS electrochemistry · 2025Article
- Diversity Oriented Clicking for Modular Synthesis.Nature reviews. Methods primers · 2025Article
- Electroreductive hydroxy fluorosulfonylation of alkenes.Nature communications · 2023Article
- Photoredox-catalyzed stereo- and regioselective vicinal fluorosulfonyl-borylation of unsaturated hydrocarbons.Chemical science · 2023Article
- An efficient and mild oxidative approach from thiols to sulfonyl derivatives with DMSO/HBr.Chemical science · 2023Article
- Organomediated electrochemical fluorosulfonylation of aryl triflates via selective C-O bond cleavage.Nature communications · 2023Article
- Recent Advances of S-ACS omega · 2023Review
- One-Pot Synthesis of Sulfonamides from Unactivated Acids and Amines via Aromatic Decarboxylative Halosulfonylation.Journal of the American Chemical Society · 2023Article
- Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides.Tetrahedron · 2023Article
- Advances in the construction of diverse SuFEx linkers.National science review · 2023Review
- Photocatalytic Sulfonyl Fluorination of Alkyl Organoboron Substrates.ACS catalysis · 2023Article
- Sulfur(VI) fluorides as tools in biomolecular and medicinal chemistry.Organic & biomolecular chemistry · 2023Review
- Facile synthesis of sulfonyl fluorides from sulfonic acids.Chemical communications (Cambridge, England) · 2023Article
- Sulfur-Phenolate Exchange: SuFEx-Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Sulfonyl fluorides are valuable synthetic motifs for a variety of applications, among which sulfur(VI) fluoride exchange-based "click chemistry" is currently the most prominent. Consequently, the development of novel and efficient synthetic methods to access these functional groups is of great interest. Herein, we report a mild and environmentally benign electrochemical approach to prepare sulfonyl fluorides using thiols or disulfides, as widely available starting materials, in combination with KF, as an inexpensive, abundant and safe fluoride source. No additional oxidants nor additional catalysts are required and, due to mild reaction conditions, the reaction displays a broad substrate scope, including a variety of alkyl, benzyl, aryl and heteroaryl thiols or disulfides.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.