ArticleThe journal of physical chemistry. B2019
Equilibrium Model for Supramolecular Copolymerizations.
Article in The journal of physical chemistry. B, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
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Who cites it
25 citing papers in PubMed.
- Co-Assemblies Regulate the Catalytic Activity of Peptide Fibrils.Angewandte Chemie (International ed. in English) · 2026Article
- PhaseTransfer: A transfer learning framework for efficient phase diagram mapping.npj computational materials · 2026Article
- Bayesian Optimization for Multicomponent Supramolecular Systems.Journal of the American Chemical Society · 2025Article
- Evolving Data-Driven Strategies for the Characterization of Supramolecular Polymers and Systems.Angewandte Chemie (International ed. in English) · 2025Review
- Tunable Thermally Activated Delayed Fluorescence from Supramolecular Polymers Toward Application in Aqueous Media.Angewandte Chemie (International ed. in English) · 2025Article
- Amplification of Asymmetry for Dynamic Helical Polymers through 1:1 Host-Guest Interactions: Theoretical Models for Majority Rule and Sergeants and Soldiers Effects.Journal of the American Chemical Society · 2025Article
- Elucidating the Boundary of Intercalation vs Sequestration in Supramolecular Polymers by Retrosynthetic Design Toward the Construction of Complex Supramolecular Systems.Angewandte Chemie (International ed. in English) · 2025Article
- Guidance on biomaterials for periodontal tissue regeneration: Fabrication methods, materials and biological considerations.Dental materials : official publication of the Academy of Dental Materials · 2025Review
- Long-Lived Triplets from Singlet Fission in Pentacene-Decorated Helical Supramolecular Polymers.Journal of the American Chemical Society · 2024Article
- Electronically and geometrically complementary perylenediimides for kinetically controlled supramolecular copolymers.Chemical science · 2024Article
- Controlling supramolecular copolymerization of alkynylplatinum(ii) terpyridine complexes: from isodesmic to cooperative mechanisms.Nanoscale advances · 2024Article
- Supramolecular copolymerization of hydrophobic and hydrophilic monomers in liquid crystalline media.Chemical science · 2024Article
- Controlling Helical Asymmetry in Supramolecular Copolymers byJournal of the American Chemical Society · 2023Article
- Straightforward model construction and analysis of multicomponent biomolecular systems in equilibrium.RSC chemical biology · 2023Article
- Simulating Assembly Landscapes for Comprehensive Understanding of Supramolecular Polymer-Solvent Systems.Journal of the American Chemical Society · 2023Article
- Elucidating the Supramolecular Copolymerization of N- and C-Centered Benzene-1,3,5-Tricarboxamides: The Role of Parallel and Antiparallel Packing of Amide Groups in the Copolymer Microstructure.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Unraveling the Complexity of Supramolecular Copolymerization Dictated by Triazine-Benzene Interactions.Journal of the American Chemical Society · 2021Article
- Temperature-dependent modulation by biaryl-based monomers of the chain length and morphology of biphenyl-based supramolecular polymers.Chemical science · 2021Article
- Assembly of Dynamic Supramolecular Polymers on a DNA Origami Platform.Angewandte Chemie (International ed. in English) · 2021Article
- Biasing the Screw-Sense of Supramolecular Coassemblies Featuring Multiple Helical States.Journal of the American Chemical Society · 2020Article
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The coassembly of different building blocks into supramolecular copolymers provides a promising avenue to control their properties and to thereby expand the potential of supramolecular polymers in applications. However, contrary to covalent copolymerization which nowadays can be well controlled, the control over sequence, polymer length, and morphology in supramolecular copolymers is to date less developed, and their structures are more determined by the delicate balance in binding free energies between the distinct building blocks than by kinetics. Consequently, to rationalize the structures of supramolecular copolymers, a thorough understanding of their thermodynamic behavior is needed. Though this is well established for single-component assemblies and over the past years several models have been proposed for specific copolymerization cases, a generally applicable model for supramolecular cooperative copolymers is still lacking. Here, we provide a generalization of our earlier mass-balance models for supramolecular copolymerizations that encompasses all our earlier models. In this model, the binding free energies of each pair of monomer types in each aggregate type can be set independently. We provide scripts to solve the model numerically for any (co)polymerization of one or two types of monomer into an arbitrary number of distinct aggregate types. We illustrate the applicability of the model on data from literature as well as on new experimental data of triarylamine triamide-based copolymers in three distinct solvents. We show that apart from common properties such as the degree of polymerization and length distributions, our approach also allows us to investigate properties such as the copolymer microstructure, that is, the internal ordering of monomers within the copolymers. Moreover, we show that in some cases, also intriguing analytical approximations can be derived from the mass balances.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.