ArticleOrigins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life2019
The Limited Roles of Autocatalysis and Enantiomeric Cross-Inhibition in Achieving Homochirality in Dilute Systems.
Article in Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- Determining the Diastereoselectivity of the Formation of Dipeptidonucleotides by NMR Spectroscopy.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Chiral Symmetry Breaking in Large Peptide Systems.Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life · 2020Article
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Abstract
To understand the effects of fluctuations on achieving homochirality, we employ a Monte-Carlo method where autocatalysis and enantiomeric cross-inhibition, as well as racemization and deracemization reactions are included. The results of earlier work either without autocatalysis or without cross-inhibition are reproduced. Bifurcation diagrams and the dependencies of the number of reaction steps on parameters are studied. In systems with 30,000 molecules, for example, up to a billion reaction steps may be needed to achieve homochirality without autocatalysis.
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