ReviewAngewandte Chemie (International ed. in English)2020
Regioselective Functionalization of [2.2]Paracyclophanes: Recent Synthetic Progress and Perspectives.
Review in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 44 papers.
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Who cites it
44 citing papers in PubMed.
- Planar Chirality Directs Enantiospecific Diastereoselectivity in Isocyanide-Based Multicomponent Reactions.ACS organic & inorganic Au · 2026Article
- Synthesis and Properties of Optically Active X-Shaped Compounds With Electron-Withdrawing Groups Based on Planar Chiral [2.2]Paracyclophane.Chemistry, an Asian journal · 2026Article
- Catalytic Enantioselective Construction of Planar Chiral Heterocyclic [2.2]Paracyclophanes Enabled by Copper-Catalyzed Desymmetric Azide-Alkyne Cycloaddition.Nature communications · 2026Article
- Helical Dispiroindeno[2,1-The Journal of organic chemistry · 2026Article
- Multifaced Generation of MOF Coatings via Vapor-Phase Sublimation and Deposition Reactions.ACS applied materials & interfaces · 2026Article
- Carbene-catalytic enantioselective synthesis of chiral macrocycles.Chemical science · 2025Review
- A planar chiral organoselenium enabled enantioselective intramolecular oxidation of trisubstituted olefins.Nature communications · 2025Article
- Isothiourea-Catalysed Acylative Kinetic and Dynamic Kinetic Resolution of Planar Chiral Paracyclophanols.Angewandte Chemie (International ed. in English) · 2025Article
- Construction of planar chiral [2,2]paracyclophanes via photoinduced cobalt-catalyzed desymmetric addition.Nature communications · 2025Article
- Synthesis of optically active folded cyclic dimers and trimers.Beilstein journal of organic chemistry · 2025Article
- Synthesis of Mono-, Di-, Tri-, and Tetra-cationic Pyridinium and Vinylpyridinium Modified [2.2]Paracyclophanes: Modular Receptors for Supramolecular Systems.ChemistryOpen · 2024Article
- A New Class of Chiral Polyethers and Polyesters Based on the [2.2]Paracyclophane Scaffold.Polymers · 2024Article
- Rhodium(II)-Catalyzed Asymmetric Cyclopropanation and Desymmetrization of [2.2]Paracyclophanes.ACS catalysis · 2024Article
- Organocatalytic desymmetrization provides access to planar chiral [2.2]paracyclophanes.Nature communications · 2024Article
- Functionalized [2.2]Paracyclophanedienes as Monomers for Poly(ACS macro letters · 2024Article
- Aggregation-induced emission from optically active X-shaped molecules based on planar chiral [2.2]paracyclophane.Scientific reports · 2023Article
- Synergistic performance of a new bimetallic complex supported on magnetic nanoparticles for Sonogashira and C-N coupling reactions.Scientific reports · 2023Article
- Disilane-bridged architectures: an emerging class of molecular materials.Chemical science · 2023Review
- Bent and Twisted: Synthesis of an Alkoxy-Substituted (1,5)Naphthalene-paracyclophanediene.The Journal of organic chemistry · 2023Article
- Kinetic resolution of substituted amido[2.2]paracyclophanes via asymmetric electrophilic amination.Nature communications · 2023Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
[2.2]Paracyclophane (PCP) is a prevalent scaffold that is widely utilized in asymmetric synthesis, π-stacked polymers, energy materials, and functional parylene coatings that finds broad applications in bio- and materials science. In the last few years, [2.2]paracyclophane chemistry has progressed tremendously, enabling the fine-tuning of its structural and functional properties. This Minireview highlights the most important recent synthetic developments in the selective functionalization of PCP that govern distinct features of planar chirality as well as chiroptical and optoelectronic properties. Special focus is given to the function-inspired design of [2.2]paracyclophane-based π-stacked conjugated materials by transition-metal-catalyzed cross-coupling reactions. Current synthetic challenges, limitations, as well as future research directions and new avenues for advancing cyclophane chemistry are also summarized.
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