Evidence map›Paper›PMID 31282153›Full record

ArticleJournal of the American Chemical Society2019

Anion Pairs Template a Trigonal Prism with Disilver Vertices.

John P Carpenter, Charlie T McTernan, Tanya K Ronson, Jonathan R Nitschke

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.

0numbers the graph read from it
0cells of the map it votes in
19citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

19 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Low-Symmetry Face-Capped Fe(II) Tetrahedra Through Anisotropic Ligand Extension.Angewandte Chemie (International ed. in English) · 2025
    Article
  6. Article
  7. Article
  8. Article
  9. Anionic Templates Drive Conversion between a ZnJournal of the American Chemical Society · 2023
    Article
  10. Article
  11. Review
  12. Article
  13. Article
  14. Article
  15. Article
  16. Review
  17. Mixed Organometallic-Organic Hybrid Assemblies Based on the Diarsene Complex [CpChemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Article
  18. Selective Anion Binding Drives the Formation of AgJournal of the American Chemical Society · 2021
    Article
  19. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

John P CarpenterDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , U.K.ORCID http://orcid.org/0000-0002-4341-2887
Charlie T McTernanDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , U.K.ORCID http://orcid.org/0000-0003-1359-0663
Tanya K RonsonDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , U.K.ORCID http://orcid.org/0000-0002-6917-3685
Jonathan R NitschkeDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , U.K.ORCID http://orcid.org/0000-0002-4060-5122

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Here we describe the formation of a trigonal prismatic cage, utilizing 2-formyl-1,8-naphthyridine subcomponents to bind pairs of silver(I) ions in close proximity. This cage is the first example of a new class of subcomponent self-assembled polyhedral structures having bimetallic vertices, as opposed to the single metal centers that typically serve as structural elements within such cages. Our new cage self-assembles around a pair of anionic templates, which are shown by crystallographic and solution-phase data to bind within the central cavity of the structure. Many different anions serve as competent templates and guests. Elongated dianions, such as the strong oxidizing agent peroxysulfate, also serve to template and bind within the cavity of the prism. The principle of using subcomponents that have more than one spatially close, but nonchelating, binding site may thus allow access to other higher-order structures with multimetallic vertices.

Identifiers

PMID31282153
PMCPMC6756586

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.