Evidence map›Paper›PMID 31280562›Full record

ArticleJournal of the American Chemical Society2019

Asymmetric Induction and Enantiodivergence in Catalytic Radical C-H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution.

Kai Lang, Sebastian Torker, Lukasz Wojtas, X Peter Zhang

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 44 papers.

0numbers the graph read from it
0cells of the map it votes in
44citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

44 citing papers in PubMed.

  1. Stereoselective Synthesis of Aminals Through Enzyme-Catalyzed Intermolecular C(spAngewandte Chemie (International ed. in English) · 2026
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  20. Helicity Modulation in NIR-Absorbing Porphyrin-Ryleneimides.Angewandte Chemie (International ed. in English) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Kai LangDepartment of Chemistry, Merkert Chemistry Center , Boston College , Chestnut Hill, Massachusetts 02467 , United States.ORCID 0000-0003-2778-8478
Sebastian TorkerDepartment of Chemistry, Merkert Chemistry Center , Boston College , Chestnut Hill, Massachusetts 02467 , United States.
Lukasz WojtasDepartment of Chemistry , University of South Florida , Tampa , Florida 33620 , United States.
X Peter ZhangDepartment of Chemistry, Merkert Chemistry Center , Boston College , Chestnut Hill, Massachusetts 02467 , United States.ORCID 0000-0001-7574-8409

Funding

New Catalytic Systems for Stereoselective C-H AminationR01GM098777 · NIGMS · UNIVERSITY OF SOUTH FLORIDA · PI ZHANG, X. PETER · 2012 to 2019
$1.7M
NIGMS NIH HHS R01 GM098777
6 · The paper itself

Abstract

Control of enantioselectivity remains a major challenge in radical chemistry. The emergence of metalloradical catalysis (MRC) offers a conceptually new strategy for addressing this and other outstanding issues. Through the employment of

Indexed as

AminationCarbonCatalysisCobaltFree RadicalsHydrogenLigandsStereoisomerismCarbonCobaltFree RadicalsHydrogenLigands

Identifiers

PMID31280562
PMCPMC6687549

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.