ReviewAngewandte Chemie (International ed. in English)2019
Bioinspired Design Provides High-Strength Benzoxazine Structural Adhesives.
Review in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
20 citing papers in PubMed, 129 citations in OpenAlex.
- A Sustainable Adhesive Paradigm: Reversibly Reinforcing, Heat-Free Bonding with Universal Substrates.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Solution-sheared supramolecular oligomers with enhanced thermal resistance in interfacial adhesion and bulk cohesion.Nature communications · 2025Article
- Synthesis and Characterization of Bio-based Polybenzoxazine Hybrids From Vanillin, Thymol, and Carvacrol.Chemistry, an Asian journal · 2025Article
- An in-situ assembled cobweb-like adhesive with high processability.Nature communications · 2025Article
- Mucus-Inspired Supramolecular Adhesives: Exploring the Synergy between Dynamic Networks and Functional Liquids.ACS nano · 2025Review
- Study on the Preparation and Modification of a Novel Bio-Based Cardanol-Furfurylamine Oxazine Resin.Polymers · 2025Article
- Processable Bio-Based Polybenzoxazine with Tunable Toughness and Dielectric Properties.Research (Washington, D.C.) · 2025Article
- Recent Progress in the Synthesis of Benzoxazin-4-Ones, Applications in N-Directed Ortho-Functionalizations, and Biological Significance.Molecules (Basel, Switzerland) · 2024Review
- Article
- Main-Chain Benzoxazines Containing an Erythritol Acetal Structure: Thermal and Degradation Properties.Molecules (Basel, Switzerland) · 2023Article
- Recent Progress of Low Dielectric and High-Performance Polybenzoxazine-Based Composites.Polymers · 2023Review
- Recent advances in bio-based polybenzoxazines as an interesting adhesive coating.RSC advances · 2023Review
- Tough Structural Adhesives with Ultra-Resistance to Both High and Cryogenic Temperature.Polymers · 2023Article
- Porous Cellulose Acetate/Block Copolymer Membranes for the Recovery of Polyphenolic Compounds from Aquatic Environments.ACS omega · 2022Article
- Bridging wounds: tissue adhesives' essential mechanisms, synthesis and characterization, bioinspired adhesives and future perspectives.Burns & trauma · 2022Review
- Review on the Accelerated and Low-Temperature Polymerization of Benzoxazine Resins: Addition Polymerizable Sustainable Polymers.Polymers · 2021Review
- Innovative Hyperbranched Polybenzoxazine-Based Graphene Oxide-Poly(amidoamines) Nanomaterials.Polymers · 2020Article
- Molecular design principles of Lysine-DOPA wet adhesion.Nature communications · 2020Article
- The molecular mechanisms underlying mussel adhesion.Nanoscale advances · 2019Review
- Bioinspired Design Provides High-Strength Benzoxazine Structural Adhesives.Angewandte Chemie (International ed. in English) · 2019Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors at 3 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A synthetic strategy to incorporate catechol functional groups into benzoxazine thermoset monomers was developed, leading to a family of bioinspired small-molecule resins and main-chain polybenzoxazines derived from biologically available phenols. Lap-shear adhesive testing revealed a polybenzoxazine derivative with greater than 5 times improved shear strength on aluminum substrates compared to a widely studied commercial benzoxazine resin. Derivative synthesis identified the catechol moiety as an important design feature in the adhesive performance and curing behavior of this bioinspired thermoset. Favorable mechanical properties comparable to commercial resin were maintained, and glass transition temperature and char yield under nitrogen were improved. Blending of monomers with bioinspired main-chain polybenzoxazine derivatives provided formulations with enhanced shear adhesive strengths up to 16 MPa, while alloying with commercial core-shell particle-toughened epoxy resins led to shear strengths exceeding 20 MPa. These results highlight the utility of bioinspired design and the use of biomolecules in the preparation of high-performance thermoset resins and adhesives with potential utility in transportation and aerospace industries and applications in advanced composites synthesis.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.