ArticleJournal of the American Chemical Society2019
Regulating the Basicity of Metal-Oxido Complexes with a Single Hydrogen Bond and Its Effect on C-H Bond Cleavage.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed, 63 citations in OpenAlex.
- cis-Carboxylate Enhancement of Mn(III)-OH Hydrogen Atom Abstraction through PCET Thermodynamics.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- A Mononuclear Ruthenium(V)-Imido Complex With Hydrogen Bonding in the Second Coordination Sphere Forming Aziridines Without N-Substituents From Alkenes in Water.Angewandte Chemie (International ed. in English) · 2026Article
- A Redox-Active Hydrogen Bond Acceptor Enables Ligand Exchange in a Zinc Complex.Inorganic chemistry · 2025Article
- Ureas and Their Derivatives as Ligands in Transition Metal Catalysis.Tetrahedron · 2025Article
- Formation and Reactivity of an Elusive Monomeric Mn(IV)-Oxo Species Inside a Cavitand Pore.Journal of the American Chemical Society · 2025Article
- Disentangling Driving Force Effects, Polar Effects,Journal of the American Chemical Society · 2025Article
- 10-Fold Increase in Hydrogen Atom Transfer Reactivity for a Series ofJournal of the American Chemical Society · 2025Article
- Na-Promoted Bimetallic Hydroxide Nanoparticles for Aerobic C-H Activation: Catalyst Design Principles and Insights into Reaction Mechanism.ACS applied materials & interfaces · 2024Article
- Synthesis, characterization and reactivity of a Mn(III)-hydroxido complex as a biomimetic model for lipoxygenase.Journal of inorganic biochemistry · 2024Article
- Enhanced Reactivities of Iron(IV)-Oxo Porphyrin Species in Oxidation Reactions Promoted by Intramolecular Hydrogen-Bonding.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Modulation of the Bonding between Copper and a Redox-Active Ligand by Hydrogen Bonds and Its Effect on Electronic Coupling and Spin States.Journal of the American Chemical Society · 2024Article
- Polar Effects in Hydrogen Atom Transfer Reactions from a Proton-Coupled Electron Transfer (PCET) Perspective: Abstractions from Toluenes.The Journal of organic chemistry · 2023Article
- Reconciling Imbalanced and Nonadiabatic Reactivity in Transition Metal-Oxo-Mediated Concerted Proton Electron Transfer (CPET).The journal of physical chemistry letters · 2023Article
- Enhancement of Reactivity of a RuJACS Au · 2023Article
- The role of basicity in selective C-H bond activation by transition metal-oxidos.Dalton transactions (Cambridge, England : 2003) · 2023Review
- HAA by the first {Mn(iii)OH} complex with all O-donor ligands.Chemical science · 2023Article
- Variable temperature kinetic isotope effects demonstrate extensive tunnelling in the C-H activation reactivity of a transition metal-oxo complex.Chemical communications (Cambridge, England) · 2023Article
- Independent Tuning of the pInorganic chemistry · 2023Article
- Testing the Limits of Imbalanced CPET Reactivity: Mechanistic Crossover in H-Atom Abstraction by Co(III)-Oxo Complexes.Journal of the American Chemical Society · 2023Article
- Cationic Effects on the Net Hydrogen Atom Bond Dissociation Free Energy of High-Valent Manganese Imido Complexes.Journal of the American Chemical Society · 2022Article
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Authors and funding
6 authors at 1 institution in 1 country.
Funding
Abstract
The functionalization of C-H bonds is an essential reaction in biology and chemistry. Metalloenzymes that often exhibit this type of reactivity contain metal-oxido intermediates that are directly involved in the initial cleavage of the C-H bonds. Regulation of the cleavage process is achieved, in part, by hydrogen bonds that are proximal to the metal-oxido units, yet our understanding of their exact role(s) is still emerging. To gain further information into the role of H-bonds on C-H bond activation, a hybrid set of urea-containing tripodal ligands has been developed in which a single H-bond can be adjusted through changes in the properties of one ureayl N-H bond. This modularity is achieved by appending a phenyl ring with different
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.