ArticleNature communications2019
Facilitating the transmetalation step with aryl-zincates in nickel-catalyzed enantioselective arylation of secondary benzylic halides.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
8 citing papers in PubMed.
- Nickel-Catalyzed Enantioselective Coupling Reactions of Fluorinated Sorbamides with Aldehydes AffordingJournal of the American Chemical Society · 2026Article
- Intramolecular Phosphinyl-Zincation of Alkynes: A Powerful Entry to Benzophosphole Oxides.Angewandte Chemie (International ed. in English) · 2025Article
- CFNature communications · 2025Article
- Metal-Catalyzed Enantioconvergent Transformations.Chemical reviews · 2023Review
- Asymmetric construction of allylicstereogenic carbon center featuring atrifluoromethyl group via enantioselective reductive fluoroalkylation.Nature communications · 2022Article
- Copper-Catalyzed Stereospecific Transformations of Alkylboronic Esters.Journal of the American Chemical Society · 2022Article
- Organometallic catalysis under visible light activation: benefits and preliminary rationales.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2022Article
- Selective Quadruple C(spiScience · 2020Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Nickel-catalyzed asymmetric cross-coupling of secondary alkyl electrophiles with different nucleophiles represents a powerful strategy for the construction of chiral tertiary carbon centers. Yet, the use of aryl Grignard reagents or aryl zinc halides in many reactions typically resulted in low enantioselectivity, mainly due to their slow transmetalation step in the catalytical cycle and consequently the requirement of relatively high temperature. Here we report that the use of lithium aryl zincate [Ph
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Registered trials
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