ArticleChemistry (Weinheim an der Bergstrasse, Germany)2019
Photochemistry with Cyanines in the Near Infrared: A Step to Chemistry 4.0 Technologies.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
11 citing papers in PubMed.
- Biomass-derived carbon dots for the initiation of conventional radical and ATRP-based photopolymerization processes.Nature protocols · 2025Review
- Rational Selection of Cyanines to Generate Conjugate Acid and Free Radicals for Photopolymerization upon Exposure at 860 nm.Angewandte Chemie (International ed. in English) · 2021Article
- Distinct Sustainable Carbon Nanodots Enable Free Radical Photopolymerization, Photo-ATRP and Photo-CuAAC Chemistry.Angewandte Chemie (International ed. in English) · 2021Article
- Cyanine-based near infra-red organic photoredox catalysis.Chemical science · 2021Article
- NIR-Sensitized Cationic and Hybrid Radical/Cationic Polymerization and Crosslinking.Angewandte Chemie (International ed. in English) · 2021Article
- Rapid High-Resolution Visible Light 3D Printing.ACS central science · 2020Article
- NIR-Sensitized Activated Photoreaction between Cyanines and Oxime Esters: Free-Radical Photopolymerization.Angewandte Chemie (International ed. in English) · 2020Article
- Carbon Dots as a Promising Green Photocatalyst for Free Radical and ATRP-Based Radical Photopolymerization with Blue LEDs.Angewandte Chemie (International ed. in English) · 2020Article
- Photophysics and photochemistry of NIR absorbers derived from cyanines: key to new technologies based on chemistry 4.0.Beilstein journal of organic chemistry · 2020Review
- Photochemistry with Cyanines in the Near Infrared: A Step to Chemistry 4.0 Technologies.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
- Dyes in modern organic chemistry.Beilstein journal of organic chemistry · 2019Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
Abstract
Cyanines covering the absorption in the near infrared (NIR) are attractive for distinct applications. They can interact either with lasers exhibiting line-shaped focus emitting at both 808 and 980 nm or bright high intensity NIR-LEDs with 805 nm emission, respectively. This is drawing attention to Industry 4.0 applications. The major deactivation occurs through a non-radiative process resulting in the release of heat into the surrounding, although a small fraction of radiative deactivation also takes place. Most of these NIR-sensitive systems possess an internal activation barrier to react in a photonic process with initiators resulting in the generation of reactive radicals and acidic cations. Thus, the heat released by the NIR absorber helps to bring the system, consisting of an NIR sensitizer and initiator, above such internal barriers. Molecular design strategies making these systems more compatible with distinct applications in a certain oleophilic surrounding are considered as a big challenge. This includes variations of the molecular pattern and counter ions derived from super acids exhibiting low coordinating properties. Further discussion focusses on the use of such systems in Chemistry 4.0 related applications. Intelligent software tools help to improve and optimize these systems combining chemistry, engineering based on high-throughput formulation screening (HTFS) technologies, and machine learning algorithms to open up novel solutions in material sciences.
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Registered trials
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