ArticleJournal of Raman spectroscopy : JRS2019
Infrared and Raman spectra of lignin substructures: Coniferyl alcohol, abietin, and coniferyl aldehyde.
Article in Journal of Raman spectroscopy : JRS, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 36 papers.
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Who cites it
36 citing papers in PubMed.
- Effect of long-term heat stress on structure and function of epidermal tissues in needles of treeline conifer seedlings.Tree physiology · 2026Article
- Development of a New FT-Raman Method for the Investigation of Cinnamon Authenticity.Foods (Basel, Switzerland) · 2026Article
- Article
- Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel.Materials (Basel, Switzerland) · 2025Article
- Electrochemical Lignin Oxidation Reaction on CuO:Langmuir : the ACS journal of surfaces and colloids · 2025Article
- Multiscale interface engineering enables strong and water resistant wood bonding.Nature communications · 2025Article
- Exploring the potential of microscopic hyperspectral, Raman, and LIBS for nondestructive quality assessment of diverse rice samples.Plant methods · 2025Article
- Multimodal imaging analysis in silver fir reveals coordination in cellulose and lignin deposition.Plant physiology · 2024Article
- Silica Biomineralization with Lignin Involves Si-O-C Bonds That Stabilize Radicals.Biomacromolecules · 2024Article
- Integrated metabolomic and transcriptomic analyses provide insights into regulation mechanisms during bulbous stem development in the Chinese medicinal herb plant, Stephania kwangsiensis.BMC plant biology · 2024Article
- Submicron- and nanoplastic detection at low micro- to nanogram concentrations using gold nanostar-based surface-enhanced Raman scattering (SERS) substrates.Environmental science. Nano · 2024Article
- Raman developmental markers in root cell walls are associated with lodging tendency in tef.Planta · 2024Article
- Deposition of silica in sorghum root endodermis modifies the chemistry of associated lignin.Frontiers in plant science · 2024Article
- Lignin accumulation in cell wall plays a role in clubroot resistance.Frontiers in plant science · 2024Article
- Article
- Pinaceae Pine Resins (Black Pine, Shore Pine, Rosin, and Baltic Amber) as Natural Dielectrics for Low Operating Voltage, Hysteresis-Free, Organic Field Effect Transistors.Global challenges (Hoboken, NJ) · 2023Article
- Impact of Low Lithium Concentrations on the Fatty Acids and Elemental Composition ofMolecules (Basel, Switzerland) · 2023Article
- Influence of Biochar and Bio-Oil Loading on the Properties of Epoxy Resin Composites.Polymers · 2023Article
- Peeling back the layers: Raman imaging reveals microchemistry of tomato cuticle during development.Plant physiology · 2023Article
- Structural differences of cell walls in earlywood and latewood ofFrontiers in plant science · 2023Article
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2 authors.
Funding
Abstract
Anatomical and chemical information can be linked by Raman imaging. Behind every pixel of the image is a Raman spectrum, which contains all the information as a molecular fingerprint. Yet to understand the spectra, the bands have to be assigned to components and their molecular structures. Although the lignin distribution is easily tracked in plant tissues, the assignment of the spectra is not good enough to allow in-depth analysis of the composition. Assignments of three lignin model compounds were derived from polarization measurements and quantum-chemical computations. Raman spectra of coniferyl alcohol crystals showed orientation dependence, which helped in band assignment. Abietin showed a Raman spectrum that was very similar to the spectrum of coniferyl alcohol, whereas its IR spectrum was very different due to bands of the sugar moiety. The Raman spectrum of coniferyl aldehyde is affected by the crystal order of molecules. All three compounds show much stronger band intensities than unconjugated single aromatic rings, indicating that the bulk of the lignin structure has significantly reduced contribution to Raman band intensities. Therefore, it is possible to highlight certain structures of lignin with Raman spectroscopy, because low amounts of a compound do not necessarily mean weak features in the spectrum.
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