ReviewAngewandte Chemie (International ed. in English)2020
Beyond Charge Balance: Counter-Cations in Polyoxometalate Chemistry.
Review in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 77 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
77 citing papers in PubMed, 455 citations in OpenAlex.
- Potential-Controlled Ammonium-Assisted Reversible Electrodeposition of Polyoxometalates for Hybrid Redox Flow Batteries.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Occurrence, Stabilization, and Emerging Functions of the Early-Transition Metal Oxyanions Including Polyoxometalates in Various Complex Structures.Chemistry, an Asian journal · 2026Review
- A Photocurable Covalent Polyoxometalates-Membrane With Hierarchical Proton Conduction Pathways for High-Performance Vanadium Flow Batteries.Angewandte Chemie (International ed. in English) · 2026Article
- Graphene Oxide-Supported Chromium-Containing Polyoxometalate as an Efficient Heterogeneous Catalyst for Nitroarene Reduction Under Mild Conditions.Global challenges (Hoboken, NJ) · 2026Article
- Molecular Structure-Tribological Performance Relationship in Tungsten-Based Polyoxometalate Ionic Liquid Lubricant Additives.ACS omega · 2026Article
- POMsDB: a QM derived molecular properties and parameters database for Polyoxometalates.Scientific data · 2026Article
- Activation of Inorganic Ligands by Interfacial Charge Transfer from a Complexation-Generated Valence Band at the Surface of a Metal Oxide Nanocrystal.Journal of the American Chemical Society · 2026Article
- Silver Cluster-Mediated Polyoxotantalate 1D Molecular Heterostructure Toward Ultra-Low-Loss Active Optical Waveguides and Information Coding.Angewandte Chemie (International ed. in English) · 2026Article
- One-Step Electrosynthesis of Polyoxometalate-Based Organic-Inorganic Hybrid Polymers and Their Confinement in Vertically Oriented Mesoporous Silica.Small methods · 2026Article
- Article
- Atomically Precise Bismuth Oxido Nanoclusters as Hosts for LnInorganic chemistry · 2026Article
- Co-templating of polyoxoniobates and silicate/germanate trimer-rings in crystals and inorganic gels.Chemical science · 2026Article
- Effects of Supporting Electrolyte and Solvent on the Thermodynamics and Kinetics of Reduction Reactions in a Keggin-Type Polyoxotungstate.Inorganic chemistry · 2026Article
- Oxidation State Determines Solvent Structure Around a Manganese-Vanadium Polyoxometalate Water-Oxidation Catalyst.Angewandte Chemie (International ed. in English) · 2026Article
- Ion-Size Controlled Non-Classical Crystallization of Metal-Oxide Nanoparticles Covered with a Few Highly Charged Ligands.Journal of the American Chemical Society · 2026Article
- Ultraselective sequestration of LiScience advances · 2025Article
- Revealing intracochlear microtrauma during cochlear implantation using optical coherence tomography and electrochemical sensing.Scientific reports · 2025Article
- Surface-Exposed Pd Nanocluster Confined within a Ring-Shaped Polyoxometalate for Selective Hydrogenation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Alkali Counterion-Dependent Crystallization of Uranium(IV)-Chloro Structural Units.Inorganic chemistry · 2025Article
- Unravelling 100-Year-Old Mystery of Rosenheim's Transition-Metal Paramolybdate Complexes.Inorganic chemistry · 2025Article
17 more citing papers are in PubMed but not listed here.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors at 2 institutions in 2 countries.
Funding
Abstract
Polyoxometalates (POMs) are molecular metal-oxide anions applied in energy conversion and storage, manipulation of biomolecules, catalysis, as well as materials design and assembly. Although often overlooked, the interplay of intrinsically anionic POMs with organic and inorganic cations is crucial to control POM self-assembly, stabilization, solubility, and function. Beyond simple alkali metals and ammonium, chemically diverse cations including dendrimers, polyvalent metals, metal complexes, amphiphiles, and alkaloids allow tailoring properties for known applications, and those yet to be discovered. This review provides an overview of fundamental POM-cation interactions in solution, the resulting solid-state compounds, and behavior and properties that emerge from these POM-cation interactions. We will explore how application-inspired research has exploited cation-controlled design to discover new POM materials, which in turn has led to the quest for fundamental understanding of POM-cation interactions.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.