Evidence map›Paper›PMID 31250959›Full record

ArticleAngewandte Chemie (International ed. in English)2019

Nickel-Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron-Substituted Quaternary Carbons and Regiodivergent Reactions.

Liang-An Chen, Alan R Lear, Pin Gao, M Kevin Brown

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.

0numbers the graph read from it
0cells of the map it votes in
18citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

18 citing papers in PubMed.

  1. Article
  2. Ni-Catalyzed 1,1- and 1,3-Aminoboration of Unactivated Alkenes.Journal of the American Chemical Society · 2023
    Article
  3. Article
  4. Article
  5. Photosensitized [2+2]-Cycloadditions of Alkenylboronates and Alkenes.Angewandte Chemie (International ed. in English) · 2022
    Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Article
  11. Construction of congested CspChemical science · 2021
    Article
  12. Article
  13. Article
  14. Article
  15. Article
  16. Nickel-Catalyzed Arylboration of Cyclopentene.Organic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicals · 2020
    Article
  17. Article
  18. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Liang-An ChenDepartment of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN, 47405, USA.
Alan R LearDepartment of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN, 47405, USA.
Pin GaoDepartment of Chemistry, School of Science, Xi'an Key Laboratory of Sustainable Energy Material Chemistry, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, Xi'an, Shaanxi, 710049, China.
M Kevin BrownDepartment of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN, 47405, USA.ORCID http://orcid.org/0000-0002-4993-0917

Funding

Methods and Strategies for Chemical SynthesisR35GM131755 · NIGMS · TRUSTEES OF INDIANA UNIVERSITY · PI Michael Kevin Brown · 2019 to 2026
$4.0M
Development of New Catalytic Reactions for Chemical SynthesisR01GM114443 · NIGMS · TRUSTEES OF INDIANA UNIVERSITY · PI BROWN, MICHAEL KEVIN · 2015 to 2019
$1.4M
National Institute of General Medical Sciences R01GM114443National Institute of General Medical Sciences R35GM131755NIGMS NIH HHS R01 GM114443NIGMS NIH HHS R35 GM131755
6 · The paper itself

Abstract

A method for the construction of boron-substituted quaternary carbons or diarylquaternary carbons by arylboration of highly substituted alkenylarenes is presented. A wide range of alkenes and arylbromides can participate in this reaction thus allowing for a diverse assortment of products to be prepared. In addition, a solvent dependent regiodivergent arylboration of 1,2-disubstituted alkenylarenes is presented, thus greatly increasing the scope of products that can be accessed.

Indexed as

alkenesarylborationboroncross couplingnickel

Identifiers

PMID31250959
PMCPMC6663602

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.