ArticleNature communications2019
Direct electrochemical oxidation of alcohols with hydrogen evolution in continuous-flow reactor.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 29 papers.
What it found
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Who cites it
29 citing papers in PubMed, 204 citations in OpenAlex.
- Colombiains A-C, Three New Alkaloids From the Soft Coral-Derived Fungus Cladosporium colombiae CSGL 10M10.Chemistry & biodiversity · 2026Article
- An Aryl Alcohol Oxidase-Peroxygenase Catalyst System Enables Efficient Alcohol to Aldehyde Transformation.Organic process research & development · 2026Article
- Spontaneous Chemical Amine Oxidation in Organic Solvents Paired With Electrochemical Hydrogen Production.Angewandte Chemie (International ed. in English) · 2026Article
- Unraveling the hidden conditions in NiOOH for electrocatalytic oxidation of methanol to formaldehyde with unity Faraday efficiency and selectivity.Chemical science · 2026Article
- Electrochemical Direct Benzylic C-H Hydroxylation with HCommunications chemistry · 2026Article
- Operando Investigation of Mechanochemically Synthesized Ni-Based Metal-Organic Frameworks for Electrocatalytic Alcohol Oxidation.ChemSusChem · 2026Article
- Photosynergetic ligand-exchange for modular synthesis of copper nanoclusters.Nature communications · 2026Article
- Electrochemistry Facilitates the Chemoselectivity of Benzylic Alcohol Oxidations Mediated by Flavin-Based Photoredox Catalysis.Organic letters · 2026Article
- Computational Electrosynthesis: A Perspective on Mechanistic Questions, Methodological Approaches, and Elucidating the Role of the Electrical Double Layer.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Review
- ECE vs DISP Mechanisms in Anodic Electrolysis of Benzyl Alcohols: Computational Prediction of Microscopic Rate Constants.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Ultrasound-Assisted Microcontinuous Process Facilitates the Selective Deuteration of Steroid Hormones.Journal of labelled compounds & radiopharmaceuticals · 2025Article
- Tuning the d-Band Center of Nickel Bimetallic Compounds for Glycerol Chemisorption: A Density Functional Study.Molecules (Basel, Switzerland) · 2025Article
- Electrocatalytic continuous flow chlorinations with iodine(I/III) mediators.Nature communications · 2024Article
- Continuous Flow Oxidation of Alcohols Using TEMPO/NaOCl for the Selective and Scalable Synthesis of Aldehydes.Organic process research & development · 2024Article
- Combining anodic alcohol oxidative coupling for C-C bond formation with cathodic ammonia production.National science review · 2024Article
- Electrocatalytic functional group conversion-based carbon resource upgrading.Chemical science · 2024Review
- Electrochemical oxidation of concentrated benzyl alcohol to high-purity benzaldehyde via superwetting organic-solid-water interfaces.Science advances · 2024Article
- Electrochemical hydrogenation and oxidation of organic species involving water.Nature reviews. Chemistry · 2024Review
- Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones.RSC advances · 2023Article
- Understanding the Oxidative Properties of Nickel Oxyhydroxide in Alcohol Oxidation Reactions.ACS catalysis · 2023Article
Corrections and comments
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Authors and funding
6 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Alcohol oxidation reactions are widely used for the preparation of aldehydes and ketones. The electrolysis of alcohols to carbonyl compounds have been underutilized owing to low efficiency. Herein, we report an electrochemical oxidation of various alcohols in a continuous-flow reactor without external oxidants, base or mediators. The robust electrochemical oxidation is performed for a variety of alcohols with good functional group tolerance, high efficiency and atom economy, whereas mechanistic studies support the benzylic radical intermediate formation and hydrogen evolution. The electrochemical oxidation proves viable on diols with excellent levels of selectivity for the benzylic position.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.