ArticleAngewandte Chemie (International ed. in English)2019
Hydrogen Bond Directed ortho-Selective C-H Borylation of Secondary Aromatic Amides.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Iridium-Catalyzed ortho-Directed C-H Borylation of Nitroarenes.ACS catalysis · 2026Article
- Polymeric iridium catalysts for C-H borylation of arenes under batch and continuous flow conditions.Communications chemistry · 2026Article
- Regioselective Arene C-H Borylation with a MOF-Immobilized Iridium Bipyridine Catalyst.ACS applied materials & interfaces · 2026Article
- Controlling the Symmetry of Perylene Derivatives via SelectiveThe Journal of organic chemistry · 2025Article
- Repurposing a supramolecular iridium catalystChemical science · 2024Article
- Interrogating the Crucial Interactions at Play in the Chiral Cation-Directed Enantioselective Borylation of Arenes.ACS catalysis · 2023Article
- Site-Selective C-H Arylation of Diverse Arenes Ortho to Small Alkyl Groups.Angewandte Chemie (International ed. in English) · 2022Article
- Transition Metal Catalysis Controlled by Hydrogen Bonding in the Second Coordination Sphere.Chemical reviews · 2022Review
- Review
- Urea-Substituted Tetramethylcyclopentadienyl Ligands for Supramolecularly Accelerated RhChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Electrostatically-directed Pd-catalysis in combination with C-H activation: site-selective coupling of remote chlorides with fluoroarenes and fluoroheteroarenes.Chemical science · 2020Article
- Enantioselective oxygenation of exocyclic methylene groups by a manganese porphyrin catalyst with a chiral recognition site.Chemical science · 2020Article
- Hydrogen Bond Directed ortho-Selective C-H Borylation of Secondary Aromatic Amides.Angewandte Chemie (International ed. in English) · 2019Article
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Authors and funding
3 authors.
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Abstract
Reported is an iridium catalyst for ortho-selective C-H borylation of challenging secondary aromatic amide substrates, and the regioselectivity is controlled by hydrogen-bond interactions. The BAIPy-Ir catalyst forms three hydrogen bonds with the substrate during the crucial activation step, and allows ortho-C-H borylation with high selectivity. The catalyst displays unprecedented ortho selectivities for a wide variety of substrates that differ in electronic and steric properties, and the catalyst tolerates various functional groups. The regioselective C-H borylation catalyst is readily accessible and converts substrates on gram scale with high selectivity and conversion.
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