Evidence map›Paper›PMID 31234486›Full record

ArticleMolecules (Basel, Switzerland)2019

A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes.

Luca Leoni, Andrea Carletta, Luca Fusaro, Jean Dubois, Nikolay A Tumanov, Carmela Aprile, Johan Wouters, Antonella Dalla Cort

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Biphasic mechanochemistry of single-chain polymerization.Proceedings of the National Academy of Sciences of the United States of America · 2025
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Luca LeoniUniversità di Roma La Sapienza, Piazzale Aldo Moro 5, 00185 Roma, Italy. luca.leoni@uniroma1.it.
Andrea CarlettaNamur Institute of Structured Matter (NISM) and Namur Research Institute for Life Sciences (NARILIS), University of Namur, 61 rue de Bruxelles, B-5000 Namur, Belgium. andrea.carletta@unamur.be.
Luca FusaroNamur Institute of Structured Matter (NISM) and Namur Research Institute for Life Sciences (NARILIS), University of Namur, 61 rue de Bruxelles, B-5000 Namur, Belgium. luca.fusaro@unamur.be.ORCID 0000-0001-5301-8034
Jean DuboisNamur Institute of Structured Matter (NISM) and Namur Research Institute for Life Sciences (NARILIS), University of Namur, 61 rue de Bruxelles, B-5000 Namur, Belgium. jean.dubois@unamur.be.
Nikolay A TumanovNamur Institute of Structured Matter (NISM) and Namur Research Institute for Life Sciences (NARILIS), University of Namur, 61 rue de Bruxelles, B-5000 Namur, Belgium. nikolay.tumanov@unamur.be.ORCID 0000-0001-6898-9036
Carmela AprileNamur Institute of Structured Matter (NISM) and Namur Research Institute for Life Sciences (NARILIS), University of Namur, 61 rue de Bruxelles, B-5000 Namur, Belgium. carmela.aprile@unamur.be.ORCID 0000-0002-3193-3239
Johan WoutersNamur Institute of Structured Matter (NISM) and Namur Research Institute for Life Sciences (NARILIS), University of Namur, 61 rue de Bruxelles, B-5000 Namur, Belgium. johan.wouters@unamur.be.
Antonella Dalla CortUniversità di Roma La Sapienza, Piazzale Aldo Moro 5, 00185 Roma, Italy. antonella.dallacort@uniroma1.it.ORCID 0000-0002-5753-5036

Funding

European Cooperation in Science and Technology Action CM1402 - From molecules to crystalsSapienza Università di Roma Progetti di Ateneo 2017
6 · The paper itself

Abstract

A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by an efficient one-pot mechanosynthesis protocol. The reaction products were characterized by means of complementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction, and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSO solvates are here reported. The described simple and relatively fast (about 1 h for all derivatives) procedure is a good alternative to classical methods performed in organic solvents.

Indexed as

Chemical PhenomenaCoordination ComplexesLigandsMechanical PhenomenaModels, MolecularMolecular StructureNickelPalladiumSalicylatesSpectrum AnalysisZincCoordination ComplexesLigandsNickelPalladiumSalicylatessalophenZincmechanochemistrymetal salophen complexessalophen ligands

Identifiers

PMID31234486
PMCPMC6631197

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.