ArticleAdvanced materials (Deerfield Beach, Fla.)2019
Additive Manufacturing of 3D-Architected Multifunctional Metal Oxides.
Article in Advanced materials (Deerfield Beach, Fla.), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed.
- Recent Advances in Two-Photon Lithography of 3D Inorganic Microstructures: Glass, Ceramics, Metals, and Carbon.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Dehydration-Driven Self-Curling for Programmable Multimetallic 3D Architectures.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Recent advances in VAT photopolymerization additive manufacturing of battery electrodes: towards high-resolution 3D-printed batteries.Chemical science · 2026Review
- Hydrogel-Based Vat Photopolymerization of Ceramics and Metals with Low Shrinkages via Repeated Infusion Precipitation.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Lightweight and ultrastrong 3D nanoarchitected high-entropy ceramic metamaterials.Science advances · 2025Article
- Prospects of Nanoscience with Nanocrystals: 2025 Edition.ACS nano · 2025Review
- From Single to Multi-Material 3D Printing of Glass-Ceramics for Micro-Optics.Small methods · 2025Review
- Bioinspired Nanoscale 3D Printing of Calcium Phosphates Using Bone Prenucleation Clusters.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Recent Advances in 3D Printed Electrodes - Bridging the Nano to Mesoscale.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Additive manufacturing of hollow connected networks for solar photo-Fenton-like catalysis.RSC sustainability · 2024Article
- 3D Printing of Hierarchical Structures Made of Inorganic Silicon-Rich Glass Featuring Self-Forming Nanogratings.ACS nano · 2024Article
- Two-Photon Polymerization of Nanocomposites for Additive Manufacturing of Transparent Magnesium Aluminate Spinel Ceramics.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Low-temperature 3D printing of transparent silica glass microstructures.Science advances · 2023Article
- A Generalized Polymer Precursor Ink Design for 3D Printing of Functional Metal Oxides.Nano-micro letters · 2023Article
- White emission in 3D-printed phosphor microstructures.Chemical communications (Cambridge, England) · 2023Article
- Additive manufacturing of Zn with submicron resolution and its conversion into Zn/ZnO core-shell structures.Nanoscale · 2022Article
- Magnetically encoded 3D mesostructure with high-order shape morphing and high-frequency actuation.National science review · 2022Article
- Nanocellulose Paper Semiconductor with a 3D Network Structure and Its Nano-Micro-Macro Trans-Scale Design.ACS nano · 2022Article
- 3D Laser Nanoprinting of Optically Functionalized Structures with Effective-Refractive-Index Tailorable TiONanomaterials (Basel, Switzerland) · 2021Article
- High Resolution Patterning of an Organic-Inorganic Photoresin for the Fabrication of Platinum Microstructures.Advanced materials (Deerfield Beach, Fla.) · 2021Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Additive manufacturing (AM) of complex three-dimensional (3D) metal oxides at the micro- and nanoscales has attracted considerable attention in recent years. State-of-the-art techniques that use slurry-based or organic-inorganic photoresins are often hampered by challenges in resin preparation and synthesis, and/or by the limited resolution of patterned features. A facile process for fabricating 3D-architected metal oxides via the use of an aqueous metal-ion-containing photoresin is presented. The efficacy of this process, which is termed photopolymer complex synthesis, is demonstrated by creating nanoarchitected zinc oxide (ZnO) architectures with feature sizes of 250 nm, by first patterning a zinc-ion-containing aqueous photoresin using two-photon lithography and subsequently calcining them at 500 ºC. Transmission electron microscopy (TEM) analysis reveals their microstructure to be nanocrystalline ZnO with grain sizes of 5.1 ± 1.6 nm. In situ compression experiments conducted in a scanning electron microscope show an emergent electromechanical response: a 200 nm mechanical compression of an architected ZnO structure results in a voltage drop of 0.52 mV. This photopolymer complex synthesis provides a pathway to easily create arbitrarily shaped 3D metal oxides that could enable previously impossible devices and smart materials.
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