Evidence map›Paper›PMID 31208109›Full record

ArticleMolecules (Basel, Switzerland)2019

Solid State and Solution Study on the Formation of Inorganic Anion Complexes with a Series of Tetrazine-Based Ligands.

Matteo Savastano, Celeste García-Gallarín, Claudia Giorgi, Paola Gratteri, Maria Dolores López de la Torre, Carla Bazzicalupi, Antonio Bianchi, Manuel Melguizo

Open access · goldAbstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
1.0field-weighted citation impact, top 28% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 18 citations in OpenAlex.

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  5. Stabilisation of Exotic Tribromide (BrMolecules (Basel, Switzerland) · 2020
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 2 institutions in 2 countries.

Matteo SavastanoDepartment of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia, 3-13, 50019 Sesto Fiorentino, Italy. matteo.savastano@unifi.it.ORCID 0000-0002-9780-7542
Celeste García-GallarínDepartment of Inorganic and Organic Chemistry, University of Jaén, 23071 Jaén, Spain. cgarcia@ujaen.es.
Claudia GiorgiDepartment of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia, 3-13, 50019 Sesto Fiorentino, Italy. claudia.giorgi@unifi.it.ORCID 0000-0003-1240-2405
Paola GratteriDepartment of NEUROFARBA-Pharmaceutical and Nutraceutical Section, and Laboratory of Molecular Modeling Cheminformatics & QSAR, University of Florence, Via Ugo Schiff 6, 50019 Sesto Fiorentino, Italy. paola.gratteri@unifi.it.ORCID 0000-0002-9137-2509
Maria Dolores López de la TorreDepartment of Inorganic and Organic Chemistry, University of Jaén, 23071 Jaén, Spain. mdlopez@ujaen.es.
Carla BazzicalupiDepartment of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia, 3-13, 50019 Sesto Fiorentino, Italy. carla.bazzicalupi@unifi.it.ORCID 0000-0003-4602-0405
Antonio BianchiDepartment of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia, 3-13, 50019 Sesto Fiorentino, Italy. antonio.bianchi@unifi.it.ORCID 0000-0002-1082-3911
Manuel MelguizoDepartment of Inorganic and Organic Chemistry, University of Jaén, 23071 Jaén, Spain. mmelgui@ujaen.es.ORCID 0000-0002-2210-9547
University of Florence · ITUniversidad de Jaén · ES

Funding

Ministero dell'Istruzione, dell'Università e della Ricerca 2015MP34H3Ministry of Economy and Competitiveness (MINECO), Spain MAT2014-60104-C2-2-R
6 · The paper itself

Abstract

Four molecules (L1-L4) constituted by an s-tetrazine ring appended with two identical aliphatic chains of increasing length bearing terminal morpholine groups were studied as anion receptors in water. The basicity properties of these molecules were also investigated. Speciation of the anion complexes formed in solution and determination of their stability constants were performed by means of potentiometric (pH-metric) titrations, while further information was obtained by NMR and isothermal titration calorimetry (ITC) measurements. The crystal structures of two neutral ligands (L3, L4) and of their H

Indexed as

AnionsCrystallography, X-RayHeterocyclic CompoundsHydrogen BondingInorganic ChemicalsLigandsMolecular StructureSaltsSolutionsWaterAnionsHeterocyclic CompoundsInorganic ChemicalsLigandsSaltsSolutionsWateranion complexesanion–π interactionscomplexation enthalpycrystal structuresH bondinglone pair–π interactionsstability constantss-tetrazinessupramolecular forces

Identifiers

PMID31208109
PMCPMC6631435
OpenAlexW2951184866

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.