Evidence map›Paper›PMID 31206937›Full record

ReviewAngewandte Chemie (International ed. in English)2019

σ-Noninnocence: Masked Phenyl-Cation Transfer at Formal Ni

Jelte S Steen, Gerald Knizia, Johannes E M N Klein

Abstract readReview
In one paragraph

Review in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.

0numbers the graph read from it
0cells of the map it votes in
14citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

14 citing papers in PubMed.

  1. Article
  2. Article
  3. A Crystalline NiXJournal of the American Chemical Society · 2024
    Article
  4. Copper-Mediated -CF(OCFACS organic & inorganic Au · 2024
    Article
  5. Article
  6. Scrutinizing formally NiChemical science · 2023
    Article
  7. Article
  8. Formation and Reactivity of a Fleeting NiAngewandte Chemie (International ed. in English) · 2022
    Article
  9. Revisiting Formal Copper(III) Complexes: Bridging Perspectives withEuropean journal of inorganic chemistry · 2022
    Review
  10. Article
  11. Article
  12. High-Valent NiMolecules (Basel, Switzerland) · 2020
    Review
  13. The Myth of dJournal of the American Chemical Society · 2019
    Article
  14. σ-Noninnocence: Masked Phenyl-Cation Transfer at Formal NiAngewandte Chemie (International ed. in English) · 2019
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Jelte S SteenMolecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, 9747, AG, Groningen, The Netherlands.ORCID http://orcid.org/0000-0003-3065-9052
Gerald KniziaDepartment of Chemistry, Pennsylvania State University, 401A Chemistry Bldg, University Park, PA, 16802, USA.ORCID http://orcid.org/0000-0002-7163-4823
Johannes E M N KleinMolecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, 9747, AG, Groningen, The Netherlands.ORCID http://orcid.org/0000-0002-1290-597X

Funding

Netherlands Organisation for Scientific Research (NWO) START-UP
6 · The paper itself

Abstract

Reductive elimination is an elementary organometallic reaction step involving a formal oxidation state change of -2 at a transition-metal center. For a series of formal high-valent Ni

Indexed as

coinage metalshomolysisligand-field inversionradicalstrifluoromethyl

Identifiers

PMID31206937
PMCPMC6771483

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.