ArticleNanomaterials (Basel, Switzerland)2019
Multiwalled Carbon Nanotube Reinforced Bio-Based Benzoxazine/Epoxy Composites with NIR-Laser Stimulated Shape Memory Effects.
Article in Nanomaterials (Basel, Switzerland), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Sustainable Functional Polymer Composites: Bio-Based Systems with Tailored Properties for Civil Engineering Applications-A Review.Polymers · 2026Review
- Development of Bio-Based Benzoxazine V-fa/PEG/Carbon Black Composites: Thermal and Mechanical Properties.Polymers · 2025Article
- Article
- Shape-Memory Polymers Based on Carbon Nanotube Composites.Micromachines · 2024Review
- Development of NIR light-responsive shape memory composites based on bio-benzoxazine/bio-urethane copolymers reinforced with graphene.Nanoscale advances · 2024Article
- Mechanical properties and curing kinetics of bio-based benzoxazine-epoxy copolymer for dental fiber post.Bioresources and bioprocessing · 2023Article
- New Approach to Shape Memory Polymer Composite Production Using Alkaline Lignin-Reinforced Epoxy-Based Shape Memory Polymers.ACS omega · 2023Article
- Article
- Two-dimensional lamellar polyimide/cardanol-based benzoxazine copper polymer composite coatings with excellent anti-corrosion performance.RSC advances · 2022Article
- Article
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Authors and funding
5 authors.
Funding
Abstract
Smart materials with light-actuated shape memory effects are developed from renewable resources in this work. Bio-based benzoxazine resin is prepared from vanillin, furfurylamine, and paraformaldehyde by utilizing the Mannich-like condensation. Vanillin-furfurylamine-containing benzoxazine resin (V-fa) is subsequently copolymerized with epoxidized castor oil (ECO). When the copolymer is reinforced with multiwalled carbon nanotubes (MWCNTs), the resulting composite exhibits shape memory effects. Molecular characteristics of V-fa resin, ECO, and V-fa/ECO copolymers are obtained from Fourier transform infrared (FT-IR) spectroscopy. Curing behavior of V-fa/ECO copolymers is investigated by differential scanning calorimetry. Dynamic mechanical properties of MWCNT reinforced V-fa/ECO composites are determined by dynamic mechanical analysis. Morphological details and distribution of MWCNTs within the copolymer matrix are characterized by transmission electron microscopy. Shape memory performances of MWCNT reinforced V-fa/ECO composites are studied by shape memory tests performed with a universal testing machine. After a significant deformation to a temporary shape, the composites can be recovered to the original shape by near-infrared (NIR) laser actuation. The shape recovery process can be stimulated at a specific site of the composite simply by focusing NIR laser to that site. The shape recovery time of the composites under NIR actuation is four times faster than the shape recovery process under conventional thermal activation. Furthermore, the composites possess good shape fixity and good shape recovery under NIR actuation.
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