ArticleInorganic chemistry2019
Metal Bonding with 3d and 6d Orbitals: An EPR and ENDOR Spectroscopic Investigation of Ti
Article in Inorganic chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed, 21 citations in OpenAlex.
- Multiple quantumScience advances · 2026Article
- Metal-carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopy.Chemical science · 2024Article
- Quantifying the Influence of Covalent Metal-Ligand Bonding on Differing Reactivity of Trivalent Uranium and Lanthanide Complexes.Angewandte Chemie (International ed. in English) · 2022Article
- Cooperative Activation of COJournal of the American Chemical Society · 2022Article
- Molecular and supported Ti(iii)-alkyls: efficient ethylene polymerization driven by the π-character of metal-carbon bonds and back donation from a singly occupied molecular orbital.Chemical science · 2020Article
- Structure and dynamics of catalytically competent but labile paramagnetic metal-hydrides: the Ti(iii)-H in homogeneous olefin polymerization.Chemical science · 2020Article
Corrections and comments
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Authors and funding
7 authors at 2 institutions in 1 country.
Funding
Abstract
Accessing covalent bonding interactions between actinides and ligating atoms remains a central problem in the field. Our current understanding of actinide bonding is limited because of a paucity of diverse classes of compounds and the lack of established models. We recently synthesized a thorium (Th)-aluminum (Al) heterobimetallic molecule that represents a new class of low-valent Th-containing compounds. To gain further insight into this system and actinide-metal bonding more generally, it is useful to study their underlying electronic structures. Here, we report characterization by electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) spectroscopy of two heterobimetallic compounds: (i) a Cp
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.