ArticleJournal of the American Chemical Society2019
Operando Spectroscopic and Kinetic Characterization of Aerobic Allylic C-H Acetoxylation Catalyzed by Pd(OAc)
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- General Regio- and Diastereoselective Allylic C-H Oxygenation of Internal Alkenes.Journal of the American Chemical Society · 2024Article
- Continuous addition kinetic elucidation: catalyst and reactant order, rate constant, and poisoning from a single experiment.Chemical science · 2023Article
- Benzoquinone Cocatalyst Contributions to DAF/Pd(OAc)ACS catalysis · 2021Article
- C4-arylation and domino C4-arylation/3,2-carbonyl migration of indoles by tuning Pd catalytic modes: Pd(i)-Pd(ii) catalysisChemical science · 2021Article
- Can Donor Ligands Make Pd(OAc)Journal of the American Chemical Society · 2020Article
- Tuning the copper(II)/copper(I) redox potential for more robust copper-catalyzed C-N bond forming reactions.European journal of inorganic chemistry · 2020Article
- Base-Assisted C-H Bond Cleavage in Cross-Coupling: Recent Insights into Mechanism, Speciation, and Cooperativity.Israel journal of chemistry · 2020Article
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Authors and funding
7 authors.
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Abstract
Allylic C-H acetoxylations are among the most widely studied palladium(II)-catalyzed C-H oxidation reactions. While the principal reaction steps are well established, key features of the catalytic mechanisms are poorly characterized, including the identity of the turnover-limiting step and the catalyst resting state. Here, we report a mechanistic study of aerobic allylic acetoxylation of allylbenzene with a catalyst system composed of Pd(OAc)
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