ArticleChemical science2019
Photocatalytic carbanion generation - benzylation of aliphatic aldehydes to secondary alcohols.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
35 citing papers in PubMed.
- Mechanistic Diversity in Photoexcited Radical Redox Chemistry: A Critical Evaluation.Angewandte Chemie (International ed. in English) · 2026Review
- When less is more: harnessing optimal quencher concentrations to maximize quantum yields in TADF photoredox reactions.Chemical science · 2026Article
- Reactivity of Nitroarenes toward Alkyl Radicals Enables Direct C-H Alkylation.Journal of the American Chemical Society · 2026Article
- Photoredox-controlled chemo-divergent, regio-, and stereoselective difunctionalization of olefins via switchable SOScience advances · 2025Article
- Harnessing Photochemistry in Natural Product Synthesis: From Strategy to Applications.Journal of natural products · 2025Review
- Interfacial Photoelectrochemistry in Organic Synthesis.Angewandte Chemie (International ed. in English) · 2025Review
- Peptide-Carbazolyl Cyanobenzene Conjugates: Enabling Biomolecule Functionalization via Photoredox and Energy Transfer Catalysis.Angewandte Chemie (International ed. in English) · 2025Article
- Alkene Carboxy-Alkylation via COJournal of the American Chemical Society · 2024Article
- Hydroalkylation of styrenes enabled by boryl radical mediated halogen atom transfer.Chemical science · 2024Article
- Rapid and scalable photocatalytic C(spNature communications · 2024Article
- Photoredox-Catalyzed Generation of Tertiary Anions from Primary Amines via a Radical Polar Crossover.Angewandte Chemie (International ed. in English) · 2024Article
- Direct conversion of amino acids to oxetanol bioisosteresChemical science · 2023Article
- Shining Fresh Light on Complex Photoredox Mechanisms through Isolation of Intermediate Radical Anions.ACS catalysis · 2023Article
- Radical Hydrocarboxylation of Unactivated Alkenes via Photocatalytic Formate Activation.Journal of the American Chemical Society · 2023Article
- A Proton-Coupled Electron Transfer Strategy to the Redox-Neutral Photocatalytic COThe Journal of organic chemistry · 2023Article
- Light-Induced Access to Carbazole-1,3-dicarbonitrile: A Thermally Activated Delayed Fluorescent (TADF) Photocatalyst for Cobalt-Mediated Allylations.The Journal of organic chemistry · 2023Article
- Hybrid Catalysts for Enantioselective Photo-Phosphoric Acid Catalysis.The Journal of organic chemistry · 2023Article
- Light-driven redox deracemization of indolines and tetrahydroquinolines using a photocatalyst coupled with chiral phosphoric acid.Chemical science · 2023Article
- Formation and degradation of strongly reducing cyanoarene-based radical anions towards efficient radical anion-mediated photoredox catalysis.Nature communications · 2023Article
- Photoredox catalysis harvesting multiple photon or electrochemical energies.Beilstein journal of organic chemistry · 2023Review
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We present a redox-neutral method for the photocatalytic generation of carbanions. Benzylic carboxylates are photooxidized by single electron transfer; immediate CO
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.