ArticleChemical science2019
Scrutinizing metal-ligand covalency and redox non-innocence
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
15 citing papers in PubMed.
- Mesoporous Copper-Based Metal-Organic Framework Flakes as a Promising Platform for Electrosynthesis of Ethylene from Carbon Dioxide.Small science · 2026Article
- Nitrogen Subvalency in a Four-Member Redox Series of Iron-Sulfur Cluster Imido Complexes.Journal of the American Chemical Society · 2025Article
- Flash Communication: Boron K‑edge XAS and TDDFT Studies of Covalent Metal-Ligand Bonding in Ni(COrganometallics · 2025Article
- Analyzing the Intensities of K-Edge Transitions in XInorganic chemistry · 2024Article
- Revving up a Designed Copper Nitrite Reductase Using Non-Coded Active Site Ligands.ACS catalysis · 2024Article
- Nitrene transfer from a sterically confined copper nitrenoid dipyrrin complex.Chemical science · 2023Article
- Lewis acid-assisted reduction of nitrite to nitric and nitrous oxides via the elusive nitrite radical dianion.Nature chemistry · 2022Article
- Resonant X-ray photo-oxidation of light-harvesting iron (II/III) N-heterocyclic carbene complexes.Scientific reports · 2021Article
- Visualizing ultrafast chemical dynamics with X-rays.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
- The duality of electron localization and covalency in lanthanide and actinide metallocenes.Chemical science · 2020Article
- Electronic Structures and Reactivity Profiles of Aryl Nitrenoid-Bridged Dicopper Complexes.Journal of the American Chemical Society · 2020Article
- Synthesis, characterization and C-H amination reactivity of nickel iminyl complexes.Chemical science · 2019Article
- The Myth of dJournal of the American Chemical Society · 2019Article
- Synthesis of a copper-supported triplet nitrene complex pertinent to copper-catalyzed amination.Science (New York, N.Y.) · 2019Article
- σ-Noninnocence: Masked Phenyl-Cation Transfer at Formal NiAngewandte Chemie (International ed. in English) · 2019Review
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Nitrogen K-edge X-ray absorption spectra (XAS) were obtained for 19 transition metal complexes bearing bipyridine, ethylenediamine, ammine, and nitride ligands. Time-dependent density functional theory (TDDFT) and DFT/restricted open configuration interaction singles (DFT/ROCIS) calculations were found to predict relative N K-edge XAS peak energies with good fidelity to experiment. The average difference (|Δ
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.