Evidence map›Paper›PMID 31160961›Full record

ArticleChemical science2019

Conformer-dependent self-assembled metallacycles with photo-reversible response.

Mengqi Li, Li-Jun Chen, Zhipeng Zhang, Qianfu Luo, Hai-Bo Yang, He Tian, Wei-Hong Zhu

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Review
  2. Article
  3. Article
  4. Article
  5. Light-Powered Dissipative Assembly of Diazocine Coordination Cages.Journal of the American Chemical Society · 2022
    Article
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Mengqi LiKey Laboratory for Advanced Materials , Institute of Fine Chemicals , Shanghai Key Laboratory of Functional Materials Chemistry , Joint International Research Laboratory of Precision Chemistry and Molecular Engineering , Feringa Nobel Prize Scientist Joint Research Center , School of Chemistry and Molecular Engineering , East China University of Science and Technology , Shanghai 200237 , China . Email: whzhu@ecust.edu.cn.
Li-Jun ChenShanghai Key Laboratory of Green Chemistry and Chemical Processes , Chang-Kung Chuang Institute , School of Chemistry and Molecular Engineering , East China Normal University , Shanghai 200062 , China . Email: hbyang@chem.ecnu.edu.cn.
Zhipeng ZhangKey Laboratory for Advanced Materials , Institute of Fine Chemicals , Shanghai Key Laboratory of Functional Materials Chemistry , Joint International Research Laboratory of Precision Chemistry and Molecular Engineering , Feringa Nobel Prize Scientist Joint Research Center , School of Chemistry and Molecular Engineering , East China University of Science and Technology , Shanghai 200237 , China . Email: whzhu@ecust.edu.cn.
Qianfu LuoKey Laboratory for Advanced Materials , Institute of Fine Chemicals , Shanghai Key Laboratory of Functional Materials Chemistry , Joint International Research Laboratory of Precision Chemistry and Molecular Engineering , Feringa Nobel Prize Scientist Joint Research Center , School of Chemistry and Molecular Engineering , East China University of Science and Technology , Shanghai 200237 , China . Email: whzhu@ecust.edu.cn.
Hai-Bo YangShanghai Key Laboratory of Green Chemistry and Chemical Processes , Chang-Kung Chuang Institute , School of Chemistry and Molecular Engineering , East China Normal University , Shanghai 200062 , China . Email: hbyang@chem.ecnu.edu.cn.ORCID 0000-0003-4926-1618
He TianKey Laboratory for Advanced Materials , Institute of Fine Chemicals , Shanghai Key Laboratory of Functional Materials Chemistry , Joint International Research Laboratory of Precision Chemistry and Molecular Engineering , Feringa Nobel Prize Scientist Joint Research Center , School of Chemistry and Molecular Engineering , East China University of Science and Technology , Shanghai 200237 , China . Email: whzhu@ecust.edu.cn.
Wei-Hong ZhuKey Laboratory for Advanced Materials , Institute of Fine Chemicals , Shanghai Key Laboratory of Functional Materials Chemistry , Joint International Research Laboratory of Precision Chemistry and Molecular Engineering , Feringa Nobel Prize Scientist Joint Research Center , School of Chemistry and Molecular Engineering , East China University of Science and Technology , Shanghai 200237 , China . Email: whzhu@ecust.edu.cn.ORCID 0000-0001-9103-166X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Discrete, well-defined metallacycles and metallacages with stimuli-responsive behaviors have been largely predominated by the organic donor/metal acceptor paradigm with spontaneous formation of coordination bonds. However, light-driven self-assembly systems usually show relatively low utilization yield of photons and low fatigue resistance. Given that almost no example illustrates the different self-assembly behaviors of antiparallel and parallel conformers in the traditional photochromic diarylethene (DAE) system, here we have for the first time constructed a unique series of photoactive conformer-dependent metallacycles, focusing on the characterization and comparison of self-assembly behavior in different ligand conformers with different di-platinum(ii) acceptors. Their photoswitchable scaffold sizes and shapes are precisely controlled by photochromically separable parallel or anti-parallel conformers

Identifiers

PMID31160961
PMCPMC6510319

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.