ArticleJournal of the American Chemical Society2019
Mechanism of the Bis(imino)pyridine-Iron-Catalyzed Hydromagnesiation of Styrene Derivatives.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Synthesis and Characterization of Unusual S=1 Fe(0)-Silyl Complexes Supported by Styrene Ligands.Angewandte Chemie (International ed. in English) · 2026Article
- A Porphyrin Iron(III) π-Dication Species and its Relevance in Catalyst Design for the Umpolung of Nucleophiles.Angewandte Chemie (International ed. in English) · 2023Article
- Blurring the boundary between homogenous and heterogeneous catalysis using palladium nanoclusters with dynamic surfaces.Nature communications · 2021Article
- Dilithium Amides as a Modular Bis-Anionic Ligand Platform for Iron-Catalyzed Cross-Coupling.Organic letters · 2021Article
- Well-Defined Aryl-FeOrganometallics · 2021Article
- TMEDA in Iron-Catalyzed Hydromagnesiation: Formation of Iron(II)-Alkyl Species for Controlled Reduction to Alkene-Stabilized Iron(0).Angewandte Chemie (International ed. in English) · 2020Article
- Iron-catalysed allylation-hydrogenation sequences as masked alkyl-alkyl cross-couplings.RSC advances · 2019Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Iron-catalyzed hydromagnesiation of styrene derivatives offers a rapid and efficient method to generate benzylic Grignard reagents, which can be applied in a range of transformations to provide products of formal hydrofunctionalization. While iron-catalyzed methodologies exist for the hydromagnesiation of terminal alkenes, internal alkynes, and styrene derivatives, the underlying mechanisms of catalysis remain largely undefined. To address this issue and determine the divergent reactivity from established cross-coupling and hydrofunctionalization reactions, a detailed study of the bis(imino)pyridine iron-catalyzed hydromagnesiation of styrene derivatives is reported. Using a combination of kinetic analysis, deuterium labeling, and reactivity studies as well as in situ
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