ArticleAngewandte Chemie (International ed. in English)2019
Covalency-Driven Preservation of Local Charge Densities in a Metal-to-Ligand Charge-Transfer Excited Iron Photosensitizer.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed.
- Analysis strategies for time-resolved X-ray solution scattering at high repetition rate XFEL sources.Journal of synchrotron radiation · 2026Article
- The Role of the Lowest Excited Triplet State in Defining the Rate of Photoaquation of Hexacyanometalates.The journal of physical chemistry letters · 2024Article
- Resolving Femtosecond Solvent Reorganization Dynamics in an Iron Complex by Nonadiabatic Dynamics Simulations.Journal of the American Chemical Society · 2022Article
- Following Metal-to-Ligand Charge-Transfer Dynamics with Ligand and Spin Specificity Using Femtosecond Resonant Inelastic X-ray Scattering at the Nitrogen K-Edge.The journal of physical chemistry letters · 2021Article
- Shot noise limited soft x-ray absorption spectroscopy in solution at a SASE-FEL using a transmission grating beam splitter.Structural dynamics (Melville, N.Y.) · 2021Article
- Probing Solute-Solvent Interactions of Transition Metal Complexes Using L-Edge Absorption Spectroscopy.The journal of physical chemistry. B · 2020Article
- Chemical control of competing electron transfer pathways in iron tetracyano-polypyridyl photosensitizers.Chemical science · 2020Article
- Covalency-Driven Preservation of Local Charge Densities in a Metal-to-Ligand Charge-Transfer Excited Iron Photosensitizer.Angewandte Chemie (International ed. in English) · 2019Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Covalency is found to even out charge separation after photo-oxidation of the metal center in the metal-to-ligand charge-transfer state of an iron photosensitizer. The σ-donation ability of the ligands compensates for the loss of iron 3d electronic charge, thereby upholding the initial metal charge density and preserving the local noble-gas configuration. These findings are enabled through element-specific and orbital-selective time-resolved X-ray absorption spectroscopy at the iron L-edge. Thus, valence orbital populations around the central metal are directly accessible. In conjunction with density functional theory we conclude that the picture of a localized charge-separation is inadequate. However, the unpaired spin density provides a suitable representation of the electron-hole pair associated with the electron-transfer process.
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