ArticleProceedings of the National Academy of Sciences of the United States of America2019
Stabilization of reactive Co
Article in Proceedings of the National Academy of Sciences of the United States of America, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Sonochemical Synthesis of Cobalt-Oxo-Cubanes as Redox-Active Platform for Proton-Coupled Electron Transfer.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Synthesis of Composite Molecules of a CoChemistry, an Asian journal · 2026Article
- Tuneable electronic coupling in linked bis(cubane) cobalt-oxo clusters.Chemical science · 2026Article
- Assembly and Valence Modulation of Ordered Bimetallic MOFs for Highly Efficient Electrocatalytic Water Oxidation.Molecules (Basel, Switzerland) · 2024Article
- {CoNature communications · 2024Article
- Isolation and Crystallographic Characterization of an Octavalent CoJournal of the American Chemical Society · 2024Article
- Analyzing Stabilities of Metal-Organic Frameworks: Correlation of Stability with Node Coordination to Linkers and Degree of Node Metal Hydrolysis.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Review
- Nanoengineered Cobalt Electrocatalyst for Alkaline Oxygen Evolution Reaction.Nanomaterials (Basel, Switzerland) · 2024Article
- Heptanuclear Mixed-Valence CoInorganic chemistry · 2024Article
- A thiomolybdate cluster for visible-light-driven hydrogen evolution: comparison of homogeneous and heterogeneous approaches.Sustainable energy & fuels · 2024Article
- Molecular Catalysis of Energy Relevance in Metal-Organic Frameworks: From Higher Coordination Sphere to System Effects.Chemical reviews · 2023Review
- Tunable metal hydroxide-organic frameworks for catalysing oxygen evolution.Nature materials · 2022Article
- Electrode reconstruction strategy for oxygen evolution reaction: maintaining Fe-CoOOH phase with intermediate-spin state during electrolysis.Nature communications · 2022Article
- Structural Analysis of Molecular Materials Using the Pair Distribution Function.Chemical reviews · 2022Review
- Do multinuclear 3d metal catalysts achieve O-O bond formation via radical coupling or via water nucleophilic attack? WNA leads the way in [CoChem catalysis · 2021Article
- Atomic resolution tracking of nerve-agent simulant decomposition and host metal-organic framework response in real space.Communications chemistry · 2021Article
- Controlled hierarchical self-assembly of networked coordination nanocapsulesChemical science · 2020Article
- The Surface Chemistry of Metal Oxide Clusters: From Metal-Organic Frameworks to Minerals.ACS central science · 2020Review
- There's no place like real-space: elucidating size-dependent atomic structure of nanomaterials using pair distribution function analysis.Nanoscale advances · 2020Review
- A strategy for stabilizing the catalyst CoProceedings of the National Academy of Sciences of the United States of America · 2019Article
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13 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A major challenge to the implementation of artificial photosynthesis (AP), in which fuels are produced from abundant materials (water and carbon dioxide) in an electrochemical cell through the action of sunlight, is the discovery of active, inexpensive, safe, and stable catalysts for the oxygen evolution reaction (OER). Multimetallic molecular catalysts, inspired by the natural photosynthetic enzyme, can provide important guidance for catalyst design, but the necessary mechanistic understanding has been elusive. In particular, fundamental transformations for reactive intermediates are difficult to observe, and well-defined molecular models of such species are highly prone to decomposition by intermolecular aggregation. Here, we present a general strategy for stabilization of the molecular cobalt-oxo cubane core (Co
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