ArticleNature communications2019
Tuning porosity in macroscopic monolithic metal-organic frameworks for exceptional natural gas storage.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 39 papers.
What it found
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The trial behind it
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Who cites it
39 citing papers in PubMed.
- In-situ growth of biomimetic ion-selective membranes via confined molecular encapsulation for superior fluoride/chloride separation.Nature communications · 2026Article
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- UiO-type metal - organic frameworks as a platform for hydrogen storage studies.Science and technology of advanced materials · 2026Review
- Porous Organic Frameworks Utilizing Halogen···Halogen Interactions of X4-tetra[2,3]Thienylene (X = Br, I): Guest Dynamics and Dielectric Response.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Computational Modeling of Reticular Materials: The Past, the Present, and the Future.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Reversible Binding of Nitric Oxide in a Cu(II)-Containing Microporous Metal-Organic Framework.Molecules (Basel, Switzerland) · 2025Article
- Understanding Metal-Organic Framework Densification: Solvent Effects and the Growth of Colloidal Primary Nanoparticles in Monolithic ZIF-8.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Dual-Action NO Delivery from One Mixed Metal Metal-Organic Framework.Inorganic chemistry · 2025Article
- High-Entropy Metal-Organic Frameworks and Their Derivatives: Advances in Design, Synthesis, and Applications for Catalysis and Energy Storage.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Metal-Organic Framework and Covalent-Organic Framework-Based Aerogels: Synthesis, Functionality, and Applications.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Review
- Development of Heterometallic Annular Tetranuclear Clusters in Metal-Organic Frameworks for Methane Purification and Storage.Chem & bio engineering · 2024Article
- Macromorphological Control of Zr-Based Metal-Organic Frameworks for Hydrolysis of a Nerve Agent Simulant.ACS applied materials & interfaces · 2024Article
- Exploring the Photophysical and Mechanical Behavior of Fluorescent Metal-Organic Framework Monoliths.Chemistry of materials : a publication of the American Chemical Society · 2024Article
- Article
- Topological Data Analysis Combined with High-Throughput Computational Screening of Hydrophobic Metal-Organic Frameworks: Application to the Adsorptive Separation of C3 Components.Nanomaterials (Basel, Switzerland) · 2024Article
- Optimizing volumetric surface area of UiO-66 and its functionalized analogs through compression.RSC advances · 2023Article
- Embedded nano spin sensor for in situ probing of gas adsorption inside porous organic frameworks.Nature communications · 2023Article
- Gradient Boosted Machine Learning Model to Predict HJournal of chemical information and modeling · 2023Article
- Gel transformation as a general strategy for fabrication of highly porous multiscale MOF architectures.Chemical science · 2023Article
- Manipulating local coordination of copper single atom catalyst enables efficient CONature communications · 2023Article
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Widespread access to greener energy is required in order to mitigate the effects of climate change. A significant barrier to cleaner natural gas usage lies in the safety/efficiency limitations of storage technology. Despite highly porous metal-organic frameworks (MOFs) demonstrating record-breaking gas-storage capacities, their conventionally powdered morphology renders them non-viable. Traditional powder shaping utilising high pressure or chemical binders collapses porosity or creates low-density structures with reduced volumetric adsorption capacity. Here, we report the engineering of one of the most stable MOFs, Zr-UiO-66, without applying pressure or binders. The process yields centimetre-sized monoliths, displaying high microporosity and bulk density. We report the inclusion of variable, narrow mesopore volumes to the monoliths' macrostructure and use this to optimise the pore-size distribution for gas uptake. The optimised mixed meso/microporous monoliths demonstrate Type II adsorption isotherms to achieve benchmark volumetric working capacities for methane and carbon dioxide. This represents a critical advance in the design of air-stable, conformed MOFs for commercial gas storage.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.