ArticleChemistry (Weinheim an der Bergstrasse, Germany)2019
Crystal Structures of DOTMA Chelates from Ce
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 26 citations in OpenAlex.
- Strategies to control the geometry and symmetry around lanthanide centres for tailored luminescence and magnetism.Nature communications · 2026Article
- Protective Effect of PEG-EDTA and Its Zinc(II) Complex on Human Cells.International journal of molecular sciences · 2025Article
- Diastereoselective Synthesis of α-Aryl-Substituted LnDOTA Chelates from Achiral Starting Materials by Deracemization Under Mild Conditions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Donor Radii in Rare-Earth Complexes.Inorganic chemistry · 2023Article
- Effect of Magnetic Anisotropy on theInorganic chemistry · 2023Article
- Facile transmetallation of [SbRSC advances · 2022Article
- Lanthanide complexes with polyaminopolycarboxylates as prospective NMR/MRI diagnostic probes: peculiarities of molecular structure, dynamics and paramagnetic properties.Journal of inclusion phenomena and macrocyclic chemistry · 2022Review
- Origin of the Isomer Stability of Polymethylated DOTA Chelates Complexed with LnEuropean journal of inorganic chemistry · 2021Article
- How the Ligand Field in Lanthanide Coordination Complexes Determines Magnetic Susceptibility Anisotropy, Paramagnetic NMR Shift, and Relaxation Behavior.Accounts of chemical research · 2020Article
- Analysis of the Relaxometric Properties of Extremely Rapidly Exchanging GdInorganic chemistry · 2020Article
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Authors and funding
5 authors at 3 institutions in 1 country.
Funding
Abstract
The crystal structures of chelates formed between each stable paramagnetic lanthanide ion and the octadentate polyamino carboxylate ligand DOTMA are described. A total of 23 individual chelates structures were obtained; in each chelate the coordination geometry around the metal ion is best described as a twisted square antiprism (torsion angle -25.0°--31.4°). Despite the uniformity of the general coordination geometry provided by the DOTMA ligand, there is a considerable variation in the hydration state of each chelate. The early Ln
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