Evidence map›Paper›PMID 31119827›Full record

ArticleAngewandte Chemie (International ed. in English)2019

X-ray Magnetic Circular Dichroism Spectroscopy Applied to Nitrogenase and Related Models: Experimental Evidence for a Spin-Coupled Molybdenum(III) Center.

Joanna K Kowalska, Justin T Henthorn, Casey Van Stappen, Christian Trncik, Oliver Einsle, David Keavney, Serena DeBeer

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.

0numbers the graph read from it
0cells of the map it votes in
22citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

22 citing papers in PubMed.

  1. Article
  2. Article
  3. Biomimetic [MFeInorganic chemistry · 2025
    Article
  4. Recent Progress in Two-Dimensional Magnetic Materials.Nanomaterials (Basel, Switzerland) · 2024
    Review
  5. Review
  6. Article
  7. Article
  8. Article
  9. Partial synthetic models of FeMoco with sulfide and carbyne ligands: Effect of interstitial atom in nitrogenase active site.Proceedings of the National Academy of Sciences of the United States of America · 2021
    Article
  10. The EChemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Article
  11. Article
  12. Article
  13. Preparation and spectroscopic characterization of lyophilized Mo nitrogenase.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2021
    Article
  14. Effects of Ionic Liquids on Metalloproteins.Molecules (Basel, Switzerland) · 2021
    Review
  15. Article
  16. Review
  17. The Spectroscopy of Nitrogenases.Chemical reviews · 2020
    Review
  18. Assignment of protonatedCommunications chemistry · 2020
    Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Joanna K KowalskaInorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.ORCID 0000-0003-1314-2924
Justin T HenthornInorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.
Casey Van StappenInorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.
Christian TrncikInstitute for Biochemistry and BIOSS Centre for Biological Signalling Studies, Albert Ludwigs University of Freiburg, Albertstrasse 21, 79104, Freiburg, Germany.
Oliver EinsleInstitute for Biochemistry and BIOSS Centre for Biological Signalling Studies, Albert Ludwigs University of Freiburg, Albertstrasse 21, 79104, Freiburg, Germany.
David KeavneyArgonne National Laboratory, 9700 S. Cass Ave, Argonne, IL, 60439, USA.
Serena DeBeerInorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.ORCID 0000-0002-5196-3400

Funding

Alexander von Humboldt FoundationDeutsche Forschungsgemeinschaft DE 1877/1-1Deutsche Forschungsgemeinschaft EI 520/10FP7 Ideas: European Research Council () 310656FP7 Ideas: European Research Council () 615414Max-Planck-Gesellschaft MPI CECU.S. Department of Energy DE-AC02-06CH11357
6 · The paper itself

Abstract

Nitrogenase enzymes catalyze the reduction of atmospheric dinitrogen to ammonia utilizing a Mo-7Fe-9S-C active site, the so-called FeMoco cluster. FeMoco and an analogous small-molecule (Et

Indexed as

Circular DichroismElectron Spin Resonance SpectroscopyHumansMolybdenumNitrogenaseX-Ray TherapyMolybdenumNitrogenaseFeMo cofactornitrogenasenitrogen fixationspin couplingX-ray magnetic circular dichroism spectroscopy

Identifiers

PMID31119827
PMCPMC6772009

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.