Evidence map›Paper›PMID 31117564›Full record

ArticleThe Journal of organic chemistry2019

Ester Formation via Symbiotic Activation Utilizing Trichloroacetimidate Electrophiles.

Nivedita S Mahajani, Rowan I L Meador, Tomas J Smith, Sarah E Canarelli, Arijit A Adhikari, Jigisha P Shah, Christopher M Russo, Daniel R Wallach, Kyle T Howard, Alexandra M Millimaci and 1 more

Open access · greenAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in The Journal of organic chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
1.1field-weighted citation impact, top 23% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 21 citations in OpenAlex.

  1. Review
  2. Formation of PyrroloindolinesTetrahedron letters · 2021
    Article
  3. Article
  4. Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors at 1 institution in 1 country.

Nivedita S MahajaniDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
Rowan I L MeadorDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
Tomas J SmithDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
Sarah E CanarelliDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
Arijit A AdhikariDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
Jigisha P ShahDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
Christopher M RussoDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
Daniel R WallachDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
Kyle T HowardDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
Alexandra M MillimaciDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.
John D ChisholmDepartment of Chemistry , Syracuse University , 1-014 Center for Science and Technology , Syracuse , New York 13244 , United States.ORCID 0000-0001-9518-2393
Syracuse University · US

Funding

New Methods for the Synthesis of PyrroloindolinesR15GM116054 · NIGMS · SYRACUSE UNIVERSITY · PI CHISHOLM, JOHN DANIEL · 2015 to 2015
$318k
NIGMS NIH HHS R15 GM116054
6 · The paper itself

Abstract

Trichloroacetimidates are useful reagents for the synthesis of esters under mild conditions that do not require an exogenous promoter. These conditions avoid the undesired decomposition of substrates with sensitive functional groups that are often observed with the use of strong Lewis or Brønsted acids. With heating, these reactions have been extended to benzyl esters without electron-donating groups. These inexpensive and convenient methods should find application in the formation of esters in complex substrates.

Indexed as

ElectronsAcetamidesCarboxylic AcidsChloroacetatesEstersAcetamidesCarboxylic AcidsChloroacetatesEsterstrichloroacetamide

Identifiers

PMID31117564
PMCPMC6597275
OpenAlexW2947331307

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.