ArticleAngewandte Chemie (International ed. in English)2019
Dissipative Catalysis with a Molecular Machine.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 41 papers.
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Who cites it
41 citing papers in PubMed.
- Temporally Controlled Interconversion Between Suprasome and Supracube Structures to Regulate Catalytic Activities.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Transient Salt-Bridge-Based Supramolecular Polymers: Experiments and Theory.Journal of the American Chemical Society · 2026Article
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- Programmable molecular dethreading towards tunable drug release.Nature communications · 2025Article
- Article
- A Thiourea-Based Rotaxane Catalyst: Nucleophilic Fluorination Phase-Transfer Process Unlocked by the Mechanical Bond.Organic letters · 2025Article
- Rotaxane-catalyzed aerobic oxidation of primary alcohols.Communications chemistry · 2024Article
- Urea-Based [2]Rotaxanes as Effective Phase-Transfer Organocatalysts: Hydrogen-Bonding Cooperative Activation Enabled by the Mechanical Bond.Journal of the American Chemical Society · 2024Article
- Dynamic control of circumrotation of a [2]catenane by acid-base switching.ChemistryOpen · 2024Article
- Collective Molecular Machines: Multidimensionality and Reconfigurability.Nano-micro letters · 2024Review
- Switched "On" Transient Fluorescence Output from a Pulsed-Fuel Molecular Ratchet.Journal of the American Chemical Society · 2023Article
- Topological Entanglement of Linear Catenanes: Knots and Threadings.ACS macro letters · 2023Article
- Chemically Fueled Communication Along a Scaffolded Nanoscale Array of Squaramides.Angewandte Chemie (International ed. in English) · 2023Article
- Non-equilibrium Steady States in Catalysis, Molecular Motors, and Supramolecular Materials: Why Networks and Language Matter.Journal of the American Chemical Society · 2023Review
- Dissipative Systems Driven by the Decarboxylation of Activated Carboxylic Acids.Accounts of chemical research · 2023Article
- Transient self-assembly of metal-organic complexes.Chemical science · 2023Article
- Synchronizing Two Distinct Nano-Circular Sliding Motions in Six-Component Machinery for Double Catalysis.Angewandte Chemie (International ed. in English) · 2022Article
- A light-gated regulation of the reaction site by a cucurbit[7]uril macrocycle.Chemical science · 2022Article
- A Chemically Fuelled Molecular Automaton Displaying Programmed Migration of ZnChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Switchable aqueous catalytic systems for organic transformations.Communications chemistry · 2022Review
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6 authors.
Funding
Abstract
We report on catalysis by a fuel-induced transient state of a synthetic molecular machine. A [2]rotaxane molecular shuttle containing secondary ammonium/amine and thiourea stations is converted between catalytically inactive and active states by pulses of a chemical fuel (trichloroacetic acid), which is itself decomposed by the machine and/or the presence of additional base. The ON-state of the rotaxane catalyzes the reduction of a nitrostyrene by transfer hydrogenation. By varying the amount of fuel added, the lifetime of the rotaxane ON-state can be regulated and temporal control of catalysis achieved. The system can be pulsed with chemical fuel several times in succession, with each pulse activating catalysis for a time period determined by the amount of fuel added. Dissipative catalysis by synthetic molecular machines has implications for the future design of networks that feature communication and signaling between the components.
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