ArticleAdvanced materials interfaces2018
Dynamic Covalent Chemistry at Interfaces: Development of Tougher, Healable Composites through Stress Relaxation at the Resin-Silica Nanoparticles Interface.
Article in Advanced materials interfaces, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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Who cites it
17 citing papers in PubMed.
- Self-Recoverable, Energy-Dissipating, and Healable Chain-Extended Supramolecular Polyurethanes and Poly(urethane-urea)s for Impact-Resistant Systems.ACS applied materials & interfaces · 2026Article
- Breaking the toughness-strength trade-off in polymer nanocomposites via a mechanically interlocked interface.Nature communications · 2026Article
- Supramolecular Polymer Additives as Repairable Reinforcements for Dynamic Covalent Networks.Advanced materials (Deerfield Beach, Fla.) · 2024Article
- Enhancing the Mechanical Properties of Injectable Nanocomposite Hydrogels by Adding Boronic Acid/Boronate Ester Dynamic Bonds at the Nanoparticle-Polymer Interface.Gels (Basel, Switzerland) · 2024Article
- From Unregulated Networks to Designed Microstructures: Introducing Heterogeneity at Different Length Scales in Photopolymers for Additive Manufacturing.Chemical reviews · 2024Review
- Relaxation mechanisms in low-stress polymer networks with alternative chemistries.JADA foundational science · 2024Article
- Micromechanical interlocking structure at the filler/resin interface for dental composites: a review.International journal of oral science · 2023Review
- Designing Stress-Adaptive Dense Suspensions Using Dynamic Covalent Chemistry.Macromolecules · 2022Article
- Developments in resin-based composites.British dental journal · 2022Review
- Low-Shrinkage Resin Matrices in Restorative Dentistry-Narrative Review.Materials (Basel, Switzerland) · 2022Review
- Probing stress relaxation behavior in glassy methacrylate networks containing thio-carbamate additives.Journal of materials chemistry. B · 2021Article
- Photopolymerization shrinkage-stress reduction in polymer-based dental restoratives by surface modification of fillers.Dental materials : official publication of the Academy of Dental Materials · 2021Article
- Thiourethane filler functionalization for dental resin composites: Concentration-dependent effects on toughening, stress reduction and depth of cure.Materials science & engineering. C, Materials for biological applications · 2021Article
- The synthesis and characterization of polyorganosiloxane nanoparticles from 3-mercaptopropyltrimethoxysilane for preparation of nanocomposite films via photoinitiated thiol-ene polymerization.Turkish journal of chemistry · 2021Article
- Combined Dynamic Network and Filler Interface Approach for Improved Adhesion and Toughness in Pressure-Sensitive Adhesives.ACS applied polymer materials · 2020Article
- Dynamic covalent chemistry (DCC) in dental restorative materials: Implementation of a DCC-based adaptive interface (AI) at the resin-filler interface for improved performance.Dental materials : official publication of the Academy of Dental Materials · 2020Article
- Tunable Mechanical Anisotropy, Crack Guiding, and Toughness Enhancement in Two-Stage Reactive Polymer Networks.Advanced engineering materials · 2019Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
The interfacial region in composites that incorporate filler materials of dramatically different modulus relative to the resin phase acts as a stress concentrator and becomes a primary locus for composite failure. A novel adaptive interface (AI) platform formed by coupling moieties capable of dynamic covalent chemistry (DCC) is introduced to the resin-filler interface to promote stress relaxation. Specifically, silica nanoparticles (SNP) are functionalized with a silane capable of addition fragmentation chain transfer (AFT), a process by which DCC-active bonds are reversibly exchanged upon light exposure and concomitant radical generation, and copolymerized with a thiol-ene resin. At a fixed SNP loading of 25 wt%, the toughness (2.3 MJ m
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.