ArticleProceedings of the National Academy of Sciences of the United States of America2019
Concepts and tools for mechanism and selectivity analysis in synthetic organic electrochemistry.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Computational Electrosynthesis: A Perspective on Mechanistic Questions, Methodological Approaches, and Elucidating the Role of the Electrical Double Layer.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Review
- ECE vs DISP Mechanisms in Anodic Electrolysis of Benzyl Alcohols: Computational Prediction of Microscopic Rate Constants.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- A guide to troubleshooting metal sacrificial anodes for organic electrosynthesis.Chemical science · 2024Review
- Advanced Electroanalysis for Electrosynthesis.ACS organic & inorganic Au · 2024Review
- Cyclic voltammetry and chronoamperometry: mechanistic tools for organic electrosynthesis.Chemical Society reviews · 2024Review
- Cathodic Radical Cyclisation of Aryl Halides Using a Strongly-Reducing Catalytic Mediator in Flow.Angewandte Chemie (International ed. in English) · 2022Article
- Electrocatalysis with Molecular Transition-Metal Complexes for Reductive Organic Synthesis.JACS Au · 2022Review
- Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis.Chemical reviews · 2022Review
- Radical cation Diels-Alder reactions of arylidene cycloalkanes.Beilstein journal of organic chemistry · 2022Article
- "How Should I Think about Voltage? What Is Overpotential?": Establishing an Organic Chemistry Intuition for Electrochemistry.The Journal of organic chemistry · 2021Article
- Defluorodearomatization: A Photocatalytic Birch-Like Reduction That Enables C-C Bond Formation and Provides Access to Unnatural Cannabinoids.The Journal of organic chemistry · 2021Article
- Organic Electrochemistry: Molecular Syntheses with Potential.ACS central science · 2021Review
- Electrode Materials in Modern Organic Electrochemistry.Angewandte Chemie (International ed. in English) · 2020Review
- Transport Phenomena: Challenges and Opportunities for Molecular Catalysis in Metal-Organic Frameworks.Journal of the American Chemical Society · 2020Article
- Synthetic Photoelectrochemistry.Angewandte Chemie (International ed. in English) · 2020Review
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2 authors.
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Abstract
As an accompaniment to the current renaissance of synthetic organic electrochemistry, the heterogeneous and space-dependent nature of electrochemical reactions is analyzed in detail. The reactions that follow the initial electron transfer step and yield the products are intimately coupled with reactant transport. Depiction of the ensuing reactions profiles is the key to the mechanism and selectivity parameters. Analysis is eased by the steady state resulting from coupling of diffusion with convection forced by solution stirring or circulation. Homogeneous molecular catalysis of organic electrochemical reactions of the redox or chemical type may be treated in the same manner. The same benchmarking procedures recently developed for the activation of small molecules in the context of modern energy challenges lead to the establishment and comparison of the catalytic Tafel plots. At the very opposite, redox-neutral chemical reactions may be catalyzed by injection (or removal) of an electron from the electrode. This class of reactions has currently few, but very thoroughly analyzed, examples. It is likely that new cases will emerge in the near future.
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