Evidence map›Paper›PMID 31094513›Full record

ArticleInorganic chemistry2019

Self-Assembled Amphiphilic Janus Double Metallacycle.

Wenbo Wang, Zhixuan Zhou, Jiong Zhou, Bingbing Shi, Bo Song, Xiaopeng Li, Feihe Huang, Peter J Stang

Abstract read
In one paragraph

Article in Inorganic chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Article
  3. A Janus carbaporphyrin pseudo-dimer.Nature communications · 2024
    Article
  4. Review
  5. Article
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Wenbo WangState Key Laboratory of Chemical Engineering, Center for Chemistry of High-Performance & Novel Materials, Department of Chemistry , Zhejiang University , Hangzhou 310027 , P. R. China.ORCID http://orcid.org/0000-0002-4282-2542
Zhixuan ZhouDepartment of Chemistry , University of Utah , 315 South 1400 East, Room 2020 , Salt Lake City , Utah 84112 , United States.ORCID http://orcid.org/0000-0001-8295-5860
Jiong ZhouState Key Laboratory of Chemical Engineering, Center for Chemistry of High-Performance & Novel Materials, Department of Chemistry , Zhejiang University , Hangzhou 310027 , P. R. China.
Bingbing ShiDepartment of Chemistry , University of Utah , 315 South 1400 East, Room 2020 , Salt Lake City , Utah 84112 , United States.ORCID http://orcid.org/0000-0001-9523-5758
Bo SongDepartment of Chemistry , University of South Florida , 4202 East Fowler Avenue , Tampa , Florida 33620 , United States.ORCID http://orcid.org/0000-0002-4337-848X
Xiaopeng LiDepartment of Chemistry , University of South Florida , 4202 East Fowler Avenue , Tampa , Florida 33620 , United States.ORCID http://orcid.org/0000-0001-9655-9551
Feihe HuangState Key Laboratory of Chemical Engineering, Center for Chemistry of High-Performance & Novel Materials, Department of Chemistry , Zhejiang University , Hangzhou 310027 , P. R. China.ORCID http://orcid.org/0000-0003-3177-6744
Peter J StangDepartment of Chemistry , University of Utah , 315 South 1400 East, Room 2020 , Salt Lake City , Utah 84112 , United States.ORCID http://orcid.org/0000-0002-2307-0576

Funding

Active Delivery of Platinum Nanoimmunoconjugates to Improve Breast Cancer TherapyR01CA215157 · NCI · PROTEOGENOMICS RESEARCH INSTIT/SYS/ MED · PI OLENYUK, BOGDAN, STANG, PETER J · 2017 to 2021
$2.3M
Self-assembly of 2D metallo-supramolecules as a novel class of antimicrobial biomaterials via forming transmembrane channelsR01GM128037 · NIGMS · UNIVERSITY OF SOUTH FLORIDA · PI CAI, JIANFENG · 2018 to 2021
$1.1M
NCI NIH HHS R01 CA215157NIGMS NIH HHS R01 GM128037
6 · The paper itself

Abstract

A double metallacycle was prepared via the size-selective integrative self-sorting of four different building blocks driven by a reversible metal-ligand coordination interaction. A hydrophobic dendron was placed on a metallacycle and a hydrophilic dendron was attached to the other metallacycle, producing a two-faced Janus-type supramolecule with two distinct functionalities. In aqueous media, hierarchical self-assembly of the supramolecular system was induced by the combination of coordination interactions and hydrophobic-hydrophilic interactions resulting in the formation of micrometer-sized fiber-like structures, a morphology distinct from metallacycles bearing only one type of functionality. This study provides a versatile approach for the construction of Janus-type molecules and demonstrates that integrative self-sorting of a supramolecular coordination system can be utilized for the preparation of complex supramolecular systems with predesigned functionalities and morphologies.

Identifiers

PMID31094513
PMCPMC6690363

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.