ReviewPolymers2019
Modeling of Entangled Polymer Diffusion in Melts and Nanocomposites: A Review.
Review in Polymers, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- Recent Advancements in Sodium Alginate-Based Hydrogels Combined with Magnetic Nanoparticles for Biological Applications: A Review.Gels (Basel, Switzerland) · 2026Review
- Structure and Flow-Viscosity of Filled-Polymer-Based 3D Printing Ink: Exploration through Coarse-Grained Molecular Dynamics.ACS omega · 2026Article
- Crystallization of the β-Form of Polypropylene from the Melt with Reduced Entanglement of Macromolecules.Polymers · 2024Article
- Review
- Electrochemical Characterization of Diffusion in Polymeric vs. Monomeric Solvents.International journal of molecular sciences · 2024Article
- Phase Behavior of Polydisperse Y-Shaped Polymer Brushes under Good Solvent Conditions.Polymers · 2024Article
- Development of a novel sandwich-structured composite from biopolymers and cellulose microfibers for building envelope applications.Scientific reports · 2023Article
- Complex Monte Carlo Light-Driven Dynamics of Monomers in Functionalized Bond Fluctuation Model Polymer Chains.Materials (Basel, Switzerland) · 2023Article
- Aggregation controlled by condensate rheology.Biophysical journal · 2023Article
- Molecular Insights into the Wall Slip Behavior of Pseudoplastic Polymer Melt in Nanochannels during Micro Injection Molding.Polymers · 2022Article
- Structure and Diffusion of Ionic PDMS Melts.Polymers · 2022Article
- Molecular weaving.Nature materials · 2022Review
- Article
- Entropic barrier of topologically immobilized DNA in hydrogels.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- Article
- Article
- Polymer Conformations, Entanglements and Dynamics in Ionic Nanocomposites: A Molecular Dynamics Study.Polymers · 2020Article
- Phase Behavior of Gradient Copolymer Melts with Different Gradient Strengths Revealed by Mesoscale Simulations.Polymers · 2020Article
- Developments in Polymer Theory and Simulation.Polymers · 2019Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
This review concerns modeling studies of the fundamental problem of entangled (reptational) homopolymer diffusion in melts and nanocomposite materials in comparison to experiments. In polymer melts, the developed united atom and multibead spring models predict an exponent of the molecular weight dependence to the polymer diffusion very similar to experiments and the tube reptation model. There are rather unexplored parameters that can influence polymer diffusion such as polymer semiflexibility or polydispersity, leading to a different exponent. Models with soft potentials or slip-springs can estimate accurately the tube model predictions in polymer melts enabling us to reach larger length scales and simulate well entangled polymers. However, in polymer nanocomposites, reptational polymer diffusion is more complicated due to nanoparticle fillers size, loading, geometry and polymer-nanoparticle interactions.
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