ArticleJournal of the American Chemical Society2019
Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 26 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
26 citing papers in PubMed.
- Cobalt-Catalyzed Intramolecular C─H Silylation of Arenes.Angewandte Chemie (International ed. in English) · 2026Article
- Rationally designed Fe-cyclopentadienone with unique orientations for efficient asymmetric hydrogenation of acylsilanes.Nature communications · 2025Article
- Turning the Tables: Ligand-Centered Hydride Shuttling in Organometallic BIP-Al Systems.Inorganic chemistry · 2025Article
- Alkene Borylation-Hydrogenation Enables Highly Active, Site-Selective Cobalt-Catalyzed Borylation.Journal of the American Chemical Society · 2025Article
- Site-Selectivity of C(sp2)-H Oxidative Addition of Fluorinated Arenes with Pyridine(dicarbene) Cobalt(I) Complexes and Aryl Isomerization.Organometallics · 2025Article
- Hydrogenation of Terminal Alkenes Catalyzed by Air-Stable Mn(I) Complexes Bearing an N-Heterocyclic Carbene-Based PCP Pincer Ligand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Iron-CatalyzedJournal of the American Chemical Society · 2023Article
- Asymmetric arene hydrogenation: towards sustainability and application.Chemical Society reviews · 2023Review
- Cobalt-Catalyzed Hydrogenation Reactions Enabled by Ligand-Based Storage of Dihydrogen.ACS catalysis · 2022Article
- C(spACS catalysis · 2022Article
- Cobalt-Catalyzed Asymmetric Hydrogenation of Enamides: Insights into Mechanisms and Solvent Effects.Organometallics · 2022Article
- Cooperative C-H Bond Activation by a Low-Spin dJournal of the American Chemical Society · 2022Article
- Combining metal-metal cooperativity, metal-ligand cooperativity and chemical non-innocence in diiron carbonyl complexes.Chemical science · 2022Article
- Systematic Variation of 3d Metal Centers in a Redox-Innocent Ligand Environment: Structures, Electrochemical Properties, and Carbon Dioxide Activation.Inorganic chemistry · 2021Article
- Extensive Redox Non-Innocence in Iron Bipyridine-Diimine Complexes: a Combined Spectroscopic and Computational Study.Inorganic chemistry · 2021Article
- Iron(II) Complexes Featuring a Redox-Active Dihydrazonopyrrole Ligand.Zeitschrift fur anorganische und allgemeine Chemie · 2021Article
- Catalytic hydrogenation enabled by ligand-based storage of hydrogen.Chemical communications (Cambridge, England) · 2021Article
- Oxidative Addition of Aryl and Alkyl Halides to a Reduced Iron Pincer Complex.Journal of the American Chemical Society · 2021Article
- Iron Catalyzed Double Bond Isomerization: Evidence for an FeChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals.Chemical science · 2020Review
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2 authors.
Funding
Abstract
Homogeneous catalysis with Earth-abundant, first-row transition metals, including iron and cobalt, has gained considerable recent attention as a potentially cost-effective and sustainable alternative to more commonly and historically used precious metals. Because fundamental organometallic transformations, such as oxidative addition and reductive elimination, are two-electron processes and essential steps in many important catalytic cycles, controlling redox chemistry-in particular overcoming one-electron chemistry-has been as a central challenge with Earth-abundant metals. This Perspective focuses on approaches to impart sufficiently strong ligand fields to generate electron-rich metal complexes able to promote oxidative addition reactions where the redox changes are exclusively metal-based. Emphasis is placed on how ligand design and exploration of fundamental organometallic chemistry coupled with mechanistic understanding have been used to discover iron catalysts for the hydrogen isotope exchange in pharmaceuticals and cobalt catalysts for C(sp
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