ArticleJournal of the American Chemical Society2019
Nickel-Catalyzed Asymmetric C-Alkylation of Nitroalkanes: Synthesis of Enantioenriched β-Nitroamides.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Photoredox/Nickel Dual-Catalyzed Asymmetric C-Alkylation of Nitroalkanes with α-Bromoketones.Organic letters · 2026Article
- A General Method forOrganic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicals · 2025Article
- From Ground-State to Excited-State Activation Modes: Flavin-Dependent "Ene"-Reductases Catalyzed Non-natural Radical Reactions.Accounts of chemical research · 2024Review
- Metal-Catalyzed Enantioconvergent Transformations.Chemical reviews · 2023Review
- Photoredox-Nickel Dual-CatalyzedJournal of the American Chemical Society · 2023Article
- AsymmetricJournal of the American Chemical Society · 2023Article
- Fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect.Chemical science · 2022Review
- Enantioselective Hydrocarbamoylation of Alkenes.Angewandte Chemie (International ed. in English) · 2022Article
- DFT insight into asymmetric alkyl-alkyl bond formationChemical science · 2022Article
- Copper-Catalyzed Propargylation of Nitroalkanes.Organic letters · 2020Article
Corrections and comments
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Authors and funding
3 authors.
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Abstract
A general catalytic method for asymmetric C-alkylation of nitroalkanes using nickel catalysis is described. This method enables the formation of highly enantioenriched β-nitroamides from readily available α-bromoamides using mild reaction conditions that are compatible with a wide range of functional groups. When combined with subsequent reactions, this method allows access to highly enantioenriched products with nitrogen-bearing fully substituted carbon centers.
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Registered trials
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