ArticleACS catalysis2018
Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes.
Article in ACS catalysis, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Single-Step Synthesis of 1,2-Cyclopentanediones by Dehydrogenative Annulation of Ethylene Glycol with Secondary Alcohols.Journal of the American Chemical Society · 2025Article
- Efficient Approaches to the Design of Six-Membered Polyazacyclic Compounds-Part 1: Aromatic Frameworks.Molecules (Basel, Switzerland) · 2025Review
- Synthesis, Characterization and Application of NNN Pincer Manganese Complexes with Pyrazole Framework in α-Alkylation Reaction.Molecules (Basel, Switzerland) · 2025Article
- Unexpected activity of MgO nanoclusters for the reductive-coupling synthesis of organonitrogen chemicals with C = N bonds.Nature communications · 2025Article
- Allenyl Thianthrenium Salt: A Bench-Stable CJournal of the American Chemical Society · 2024Article
- Recent Methods for the Synthesis of Quinoxaline Derivatives and their Biological Activities.Mini reviews in medicinal chemistry · 2024Review
- Article
- Cooperative chemoenzymatic synthesis of N-heterocycles via synergizing bio- with organocatalysis.Science advances · 2022Article
- Synthesis of N-Heterocycles via Oxidant-Free Dehydrocyclization of Alcohols Using Heterogeneous Catalysts.Angewandte Chemie (International ed. in English) · 2021Review
- Multicomponent syntheses of 5- and 6-membered aromatic heterocycles using group 4-8 transition metal catalysts.Chemical science · 2021Review
- Synthesis of Tetrahydroquinolines via Borrowing Hydrogen Methodology Using a Manganese PNOrganic letters · 2020Article
- Bioretrosynthesis of FunctionalizedAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2020Article
- Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols.ACS catalysis · 2018Article
- Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium.Journal of the American Chemical Society · 2018Article
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Base-metal catalyzed dehydrogenative self-coupling of 2-amino alcohols to selectively form functionalized 2,5-substituted pyrazine derivatives is presented. Also, 2-substituted quinoxaline derivatives are synthesized by dehydrogenative coupling of 1,2-diaminobenzene and 1,2-diols. In both cases, water and hydrogen gas are formed as the sole byproducts. The reactions are catalyzed by acridine-based pincer complexes of earth-abundant manganese.
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