ArticleAngewandte Chemie (International ed. in English)2019
Halogen Bonding Helicates Encompassing Iodonium Cations.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
20 citing papers in PubMed.
- A Base-Mediated Rearrangement of the Benzylic 1,5-Hexadipyridynyl Moiety.ChemPlusChem · 2025Article
- Stabilisation of Bromenium Ions in Macrocyclic Halogen Bond Complexes.Angewandte Chemie (International ed. in English) · 2025Article
- Ortho-Substituent Effects on Halogen Bond Geometry for N-Haloimide⋯2-Substituted Pyridine Complexes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Halogen Bonds of Halogen(I) Ions─Where Are We and Where to Go?Journal of the American Chemical Society · 2024Review
- Supramolecular axial chirality in [N-I-N]Chemical science · 2023Article
- Article
- Cyclic Homo- and Heterohalogen Di-λJournal of the American Chemical Society · 2023Article
- Structure and Bonding of Halonium Compounds.Inorganic chemistry · 2023Article
- Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines.RSC advances · 2022Article
- Are bis(pyridine)iodine(I) complexes applicable for asymmetric halogenation?Organic & biomolecular chemistry · 2021Article
- Revisiting the covalent nature of halogen bonding: a polarized three-center four-electron bond.RSC advances · 2021Article
- The Influence of Secondary Interactions on the [N-I-N]Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Comment on "The Nature of Chalcogen-Bonding-Type Tellurium-Nitrogen Interactions": Fixing the Description of Finite-Temperature Effects Restores the Agreement Between Experiment and Theory.Angewandte Chemie (International ed. in English) · 2021Article
- Quantification of Noncovalent Interactions in Azide-Pnictogen, -Chalcogen, and -Halogen Contacts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Short X···N Halogen Bonds With Hexamethylenetetraamine as the Acceptor.Frontiers in chemistry · 2021Article
- Halogen Bond of Halonium Ions: Benchmarking DFT Methods for the Description of NMR Chemical Shifts.Journal of chemical theory and computation · 2020Article
- Catalytic Activity ofJournal of the American Chemical Society · 2020Article
- Effects of Halogen, Chalcogen, Pnicogen, and Tetrel Bonds on IR and NMR Spectra.Molecules (Basel, Switzerland) · 2019Article
- Halogen Bonding Helicates Encompassing Iodonium Cations.Angewandte Chemie (International ed. in English) · 2019Article
- Fluorinated azobenzenes as supramolecular halogen-bonding building blocks.Beilstein journal of organic chemistry · 2019Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors.
Funding
Abstract
The first halonium-ion-based helices were designed and synthesized using oligo-aryl/pyridylene-ethynylene backbones that fold around reactive iodonium ions. Halogen bonding interactions stabilize the iodonium ions within the helices. Remarkably, the distance between two iodonium ions within a helix is shorter than the sum of their van der Waals radii. The helical conformations were characterized by X-ray crystallography in the solid state, by NMR spectroscopy in solution and corroborated by DFT calculations. The helical complexes possess potential synthetic utility, as demonstrated by their ability to induce iodocyclization of 4-penten-1-ol.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.