Evidence map›Paper›PMID 31070901›Full record

ArticleJournal of the American Chemical Society2019

Direct Intermolecular Anti-Markovnikov Hydroazidation of Unactivated Olefins.

Hongze Li, Shou-Jie Shen, Cheng-Liang Zhu, Hao Xu

Open access · greenAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
3.0field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed, 56 citations in OpenAlex.

  1. Review
  2. Article
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  5. Article
  6. Article
  7. Comparative analysis of complanadine A total syntheses.Beilstein journal of organic chemistry · 2025
    Review
  8. Review
  9. Neurotrophic Natural Products.Progress in the chemistry of organic natural products · 2024
    Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Article
  15. Anti-Markovnikov Hydroazidation of Activated Olefins via Organic Photoredox Catalysis.Synlett : accounts and rapid communications in synthetic organic chemistry · 2020
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Hongze LiDepartment of Chemistry , Georgia State University , 100 Piedmont Avenue SE , Atlanta Georgia 30303 , United States.
Shou-Jie ShenDepartment of Chemistry , Georgia State University , 100 Piedmont Avenue SE , Atlanta Georgia 30303 , United States.ORCID 0000-0003-4110-7843
Cheng-Liang ZhuDepartment of Chemistry , Georgia State University , 100 Piedmont Avenue SE , Atlanta Georgia 30303 , United States.
Hao XuDepartment of Chemistry , Georgia State University , 100 Piedmont Avenue SE , Atlanta Georgia 30303 , United States.ORCID 0000-0001-5029-8392
Georgia State University · US

Funding

Selective Nitrogen Atom Transfer for Applications in Biomedical SciencesR35GM134926 · NIGMS · BRANDEIS UNIVERSITY · PI XU, HAO · 2020 to 2025
$2.1M
Selective Nitrogen Atom Transfer for Applications in Biomedical SciencesR01GM110382 · NIGMS · GEORGIA STATE UNIVERSITY · PI XU, HAO · 2014 to 2019
$1.9M
NIGMS NIH HHS R01 GM110382NIGMS NIH HHS R35 GM134926
6 · The paper itself

Abstract

We herein report a direct intermolecular anti-Markovnikov hydroazidation method for unactivated olefins, which is promoted by a catalytic amount of bench-stable benziodoxole at ambient temperature. This method facilitates previously difficult, direct addition of hydrazoic acid across a wide variety of unactivated olefins in both complex molecules and unfunctionalized commodity chemicals. It conveniently fills a synthetic chemistry gap of existing olefin hydroazidation procedures, and thereby provides a valuable tool for azido-group labeling in organic synthesis and chemical biology studies.

Indexed as

AlkenesAzidesCatalysisIodobenzenesMolecular StructureAlkenesAzidesIodobenzeneso-iodoxybenzoic acid

Identifiers

PMID31070901
PMCPMC6677148
OpenAlexW2944373110

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.