ArticleAngewandte Chemie (International ed. in English)2019
Strong Exchange Couplings Drastically Slow Down Magnetization Relaxation in an Air-Stable Cobalt(II)-Radical Single-Molecule Magnet (SMM).
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Introducing Diradicaloid Thiele's Hydrocarbon Derivatives as Ligand in Transition Metal Chemistry.Angewandte Chemie (International ed. in English) · 2026Article
- Cobalt(II) Single-Chain Magnet With Strong Anisotropy and Ferromagnetic IntraChain Coupling.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Experimental determination of the magnetic anisotropy in five-coordinated Co(ii) field-induced single molecule magnets.Chemical science · 2025Article
- The Spin-Phonon Relaxation Mechanism of Single-Molecule Magnets in the Presence of Strong Exchange Coupling.ACS central science · 2025Article
- Electronic structure of mononuclear and radical-bridged dinuclear cobalt(II) single-molecule magnets.Nature communications · 2025Article
- Oxygen-Donor Metalloligands Induce Slow Magnetization Relaxation in Zero Field for a Cobalt(II) Complex with {CoOInorganic chemistry · 2024Article
- Zero-Field SMM Behavior Triggered by Magnetic Exchange Interactions and a Collinear Arrangement of Local Anisotropy Axes in a Linear CoInorganic chemistry · 2023Article
- Co(II) single-ion magnets: synthesis, structure, and magnetic properties.Monatshefte fur chemie · 2022Review
- Semiquinone radical-bridged MChemical science · 2020Article
- Tuning PtChemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Single-ion anisotropy and exchange coupling in cobalt(ii)-radical complexes: insights from magnetic andChemical science · 2019Article
- Strong Exchange Couplings Drastically Slow Down Magnetization Relaxation in an Air-Stable Cobalt(II)-Radical Single-Molecule Magnet (SMM).Angewandte Chemie (International ed. in English) · 2019Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating a highly anisotropic four-coordinate cobalt(II) building block into a strongly coupled fully air- and moisture-stable three-spin system, it proved possible to suppress under-barrier Raman processes leading to 350-fold increase of magnetization relaxation time and pronounced hysteresis. Relaxation times of up to 9 hours at low temperatures were found.
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