ArticleThe journal of physical chemistry. B2019
Hydrogen Bond Networks in Binary Mixtures of Water and Organic Solvents.
Article in The journal of physical chemistry. B, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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5 citing papers in PubMed.
- The Preferential Solvation of Methyl Red in Various Binary Aqueous Solutions: Solvatochromism, Preferential Solvation Parameters, Microheterogeneity of Solvents and Polarity Scale.Journal of fluorescence · 2025Article
- Solvatochromism, Preferential Solvation and Multiparametric Approach to the Spectral Shift of Methyl Orange in Aqueous Cosolvent Mixtures.Journal of fluorescence · 2024Article
- Radial distribution and hydrogen bonded network graphs of alcohol-aniline binary mixture.Journal of molecular modeling · 2023Article
- Anomalous interfacial dynamics of single proton charges in binary aqueous solutions.Science advances · 2021Article
- Room temperature and high response ethanol sensor based on two dimensional hybrid nanostructures of WSScientific reports · 2020Article
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2 authors.
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Abstract
We here present an approach for the optical in situ characterization of hydrogen bond networks (HBNs) in binary mixtures of water and organic solvents (OSs), such as methanol, ethanol, and acetonitrile. HBNs are characterized based on (i) the analysis of experimental molar Raman spectra of the mixture, (ii) partial molar Raman spectra of the mixture constituents, and (iii) computed ideal molar Raman spectra of the mixture. Especially, the consideration of the partial molar Raman spectra provides insights into the development of hydrogen bonds of molecules of one species with their neighbors. The obtained Raman spectra are evaluated with respect to the centroid of the symmetric stretching vibration Raman signal of water and to the hydroxyl stretching vibration of alcohols. We show the influence of composition and temperature on the development of the HBN of the mixtures, the HBN of water, and the HBN of the OS molecules.
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