ArticleJournal of the American Chemical Society2019
Transition-Metal- and Light-Free Directed Amination of Remote Unactivated C(sp
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.
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Who cites it
27 citing papers in PubMed, 73 citations in OpenAlex.
- Nickel-Catalyzed α‑Arylation and Alkenylation of α‑Trifluoromethyl Amines via 1,2-HAT Assisted by DMSO.JACS Au · 2026Article
- Merging Double Hydrogen Atom Transfer and Stepwise Proton-Coupled Electron Transfer for γ‑C-H Hydrazination of Alcohols.JACS Au · 2026Article
- Cobalt-Catalyzed γ‑C-H Functionalization of Alcohols via Olefin-Tethered Radical Relay.JACS Au · 2026Article
- Photoredox-Catalyzed Site-Selective Intermolecular C(spOrganic letters · 2025Article
- Biomimetic Catalytic Remote Desaturation of Aliphatic Alcohols.Organic letters · 2025Article
- Radical Polarity.Journal of the American Chemical Society · 2024Article
- Organobismuth Compounds as Aryl Radical Precursors via Light-Driven Single-Electron Transfer.ACS catalysis · 2024Article
- 1,2-Aminoxyalkylation of alkenes with alkyl iodides and TEMPONa through SET- and XAT-processes.Chemical science · 2023Article
- Modular Synthesis of (Borylmethyl)silanes through Orthogonal Functionalization of a Carbon Atom.Organic letters · 2023Article
- Aryl Radical Enabled, Copper-Catalyzed Sonogashira-Type Cross-Coupling of Alkynes with Alkyl Iodides.ACS catalysis · 2023Article
- Transition-metal free C-N bond formation from alkyl iodides and diazonium salts via halogen-atom transfer.Nature communications · 2022Article
- General and Selective Metal-Free RadicalChem · 2022Article
- Diastereoconvergent synthesis ofChemical science · 2022Article
- Photo-Induced Ruthenium-Catalyzed Double Remote C(spAngewandte Chemie (International ed. in English) · 2022Article
- Palladium-CatalyzedACS catalysis · 2022Article
- Iminyl radical-triggered relay annulation for the construction of bridged aza-tetracycles bearing four contiguous stereogenic centers.Chemical science · 2022Article
- Visible Light-Induced Transition Metal Catalysis.Chemical reviews · 2022Review
- Photo-induced copper-catalyzed sequential 1,n-HAT enabling the formation of cyclobutanols.Nature communications · 2021Article
- Radical philicity and its role in selective organic transformations.Nature reviews. Chemistry · 2021Review
- Visible Light-Induced Pd-Catalyzed Alkyl-Heck Reaction of Oximes.ACS catalysis · 2021Article
Corrections and comments
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Authors and funding
7 authors at 1 institution in 1 country.
Funding
Abstract
Due to the great value of amino alcohols, new methods for their synthesis are in high demand. Abundant aliphatic alcohols represent the ideal feedstock for the method development toward this important motif. To date, transition-metal-catalyzed approaches for the directed remote amination of alcohols have been well established. Yet, they have certain disadvantages such as the use of expensive catalysts and limited scope. Very recently, transition-metal-free visible-light-induced radical approaches have emerged as new powerful tools for directed remote amination of alcohols. Relying on 1,5-HAT reactivity, these methods are limited to β - or δ-amination only. Herein, we report a novel transition-metal- and visible-light-free room-temperature radical approach for remote β -, γ-, and δ-C(sp
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.